1,2-cis-selective formation of a unique amino-containing amino glycoside by endocyclic cleavage strategy

Shino Manabe; Yukishige Ito

doi:10.3987/COM-18-S(F)101

1,2-cis-selective formation of a unique amino-containing amino glycoside by endocyclic cleavage strategy

Research output: Contribution to journal › Article › peer-review

Abstract

– 2-Acetamido-4-amino-2,4,6-trideoxy-α-D-galactopyranoside (AAT), a unique aminated sugar unit, is often found in zwitterionic polysaccharides. Stereoselective formation of the 1,2-cis linkage of these unique sugar derivatives was achieved by an anomerization reaction based on an endocyclic cleavage process.

Original language	English
Pages (from-to)	1-11
Number of pages	11
Journal	Heterocycles
Volume	99
Issue number	2
DOIs	https://doi.org/10.3987/COM-18-S(F)101
Publication status	Published - 2019
Externally published	Yes

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

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10.3987/COM-18-S(F)101

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title = "1,2-cis-selective formation of a unique amino-containing amino glycoside by endocyclic cleavage strategy",

abstract = "– 2-Acetamido-4-amino-2,4,6-trideoxy-α-D-galactopyranoside (AAT), a unique aminated sugar unit, is often found in zwitterionic polysaccharides. Stereoselective formation of the 1,2-cis linkage of these unique sugar derivatives was achieved by an anomerization reaction based on an endocyclic cleavage process.",

author = "Shino Manabe and Yukishige Ito",

note = "Publisher Copyright: {\textcopyright} 2019 The Japan Institute of Heterocyclic Chemistry",

year = "2019",

doi = "10.3987/COM-18-S(F)101",

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AB - – 2-Acetamido-4-amino-2,4,6-trideoxy-α-D-galactopyranoside (AAT), a unique aminated sugar unit, is often found in zwitterionic polysaccharides. Stereoselective formation of the 1,2-cis linkage of these unique sugar derivatives was achieved by an anomerization reaction based on an endocyclic cleavage process.

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1,2-cis-selective formation of a unique amino-containing amino glycoside by endocyclic cleavage strategy

Abstract

ASJC Scopus subject areas

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