1,3-Diynes synthesis by homo-coupling of terminal alkynes using a Pd(PPh3)4/Ag2O simple catalyst system

Xiujuan Feng; Ziran Zhao; Fan Yang; Tienan Jin; Yongjie Ma; Ming Bao

doi:10.1016/j.jorganchem.2011.01.022

1,3-Diynes synthesis by homo-coupling of terminal alkynes using a Pd(PPh₃)₄/Ag₂O simple catalyst system

Xiujuan Feng, Ziran Zhao, Fan Yang, Tienan Jin, Yongjie Ma, Ming Bao

SCI - Research and Analytical Center for Giant Molecules

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

Amine- and copper salt-free palladium-catalyzed homo-coupling reaction of terminal alkynes proceeded efficiently in the presence of silver(I) oxide, which served as both activator and oxidant, in tetrahydrofuran at 60 °C to achieve satisfactory yields of 1,3-diyne compounds. It was demonstrated for the first time by means of XPS analysis that Pd(0) species can be oxidated to Pd(II) by silver(I) oxide.

Original language	English
Pages (from-to)	1479-1482
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	696
Issue number	7
DOIs	https://doi.org/10.1016/j.jorganchem.2011.01.022
Publication status	Published - 2011 Apr 1

Keywords

1,3-Diyne synthesis
Homo-coupling
Palladium catalyst
Terminal alkyne

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10.1016/j.jorganchem.2011.01.022

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title = "1,3-Diynes synthesis by homo-coupling of terminal alkynes using a Pd(PPh3)4/Ag2O simple catalyst system",

abstract = "Amine- and copper salt-free palladium-catalyzed homo-coupling reaction of terminal alkynes proceeded efficiently in the presence of silver(I) oxide, which served as both activator and oxidant, in tetrahydrofuran at 60 °C to achieve satisfactory yields of 1,3-diyne compounds. It was demonstrated for the first time by means of XPS analysis that Pd(0) species can be oxidated to Pd(II) by silver(I) oxide.",

keywords = "1,3-Diyne synthesis, Homo-coupling, Palladium catalyst, Terminal alkyne",

author = "Xiujuan Feng and Ziran Zhao and Fan Yang and Tienan Jin and Yongjie Ma and Ming Bao",

note = "Funding Information: We are grateful to the National Natural Science Foundation of China (No. 20972021 ) for their financial support. This work was also supported by the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20090041110012 ) and the State Key Laboratory of Fine Chemicals ( KF0607 ). ",

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doi = "10.1016/j.jorganchem.2011.01.022",

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T1 - 1,3-Diynes synthesis by homo-coupling of terminal alkynes using a Pd(PPh3)4/Ag2O simple catalyst system

AU - Feng, Xiujuan

AU - Zhao, Ziran

AU - Yang, Fan

AU - Jin, Tienan

AU - Ma, Yongjie

AU - Bao, Ming

N1 - Funding Information: We are grateful to the National Natural Science Foundation of China (No. 20972021 ) for their financial support. This work was also supported by the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20090041110012 ) and the State Key Laboratory of Fine Chemicals ( KF0607 ).

PY - 2011/4/1

Y1 - 2011/4/1

N2 - Amine- and copper salt-free palladium-catalyzed homo-coupling reaction of terminal alkynes proceeded efficiently in the presence of silver(I) oxide, which served as both activator and oxidant, in tetrahydrofuran at 60 °C to achieve satisfactory yields of 1,3-diyne compounds. It was demonstrated for the first time by means of XPS analysis that Pd(0) species can be oxidated to Pd(II) by silver(I) oxide.

AB - Amine- and copper salt-free palladium-catalyzed homo-coupling reaction of terminal alkynes proceeded efficiently in the presence of silver(I) oxide, which served as both activator and oxidant, in tetrahydrofuran at 60 °C to achieve satisfactory yields of 1,3-diyne compounds. It was demonstrated for the first time by means of XPS analysis that Pd(0) species can be oxidated to Pd(II) by silver(I) oxide.

KW - 1,3-Diyne synthesis

KW - Homo-coupling

KW - Palladium catalyst

KW - Terminal alkyne

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DO - 10.1016/j.jorganchem.2011.01.022

M3 - Article

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SN - 0022-328X

VL - 696

SP - 1479

EP - 1482

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 7

ER -

1,3-Diynes synthesis by homo-coupling of terminal alkynes using a Pd(PPh₃)₄/Ag₂O simple catalyst system

Abstract

Keywords

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