3D observation of Hexagonally Perforated Layer (HPL) structure in block copolymer thin films

Koji Sawa; Yukihiro Nishikawa; Hiroshi Jinnai; Taihyun Chang; Toshio Nishi

3D observation of Hexagonally Perforated Layer (HPL) structure in block copolymer thin films

Koji Sawa, Yukihiro Nishikawa, Hiroshi Jinnai, Taihyun Chang, Toshio Nishi

IMRAM - Division of Measurements

Research output: Contribution to conference › Paper › peer-review

Abstract

Three-dimentional structure of poly(styrene-block-isoprene) (SI) diblock copolymer thin films was studied by means of transmission electron microtomography (TEMT). After annealing at 120°C, it was found that the SI thin film spin-coated on silicon wafer exhibited Hexagonally Perforated Layer (HPL) morphology with its lamellae highly oriented parallel to the substrate. The stacking sequences of HPL channels can be modeled as both AB-stacking and ABC-stacking patterns, as illustrated in Fig. 1. As a result of three-dimensional observation, we found that this sample formed ABC-stacking.

Original language	English
Pages	927
Number of pages	1
Publication status	Published - 2006
Event	55th SPSJ Annual Meeting - Nagoya, Japan Duration: 2006 May 24 → 2006 May 26

Conference

Conference	55th SPSJ Annual Meeting
Country/Territory	Japan
City	Nagoya
Period	06/5/24 → 06/5/26

Keywords

Block copolymer
Hexagonally Perforated Layer
Thin films
Transmission Electron Microtomography

Cite this

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title = "3D observation of Hexagonally Perforated Layer (HPL) structure in block copolymer thin films",

abstract = "Three-dimentional structure of poly(styrene-block-isoprene) (SI) diblock copolymer thin films was studied by means of transmission electron microtomography (TEMT). After annealing at 120°C, it was found that the SI thin film spin-coated on silicon wafer exhibited Hexagonally Perforated Layer (HPL) morphology with its lamellae highly oriented parallel to the substrate. The stacking sequences of HPL channels can be modeled as both AB-stacking and ABC-stacking patterns, as illustrated in Fig. 1. As a result of three-dimensional observation, we found that this sample formed ABC-stacking.",

keywords = "Block copolymer, Hexagonally Perforated Layer, Thin films, Transmission Electron Microtomography",

author = "Koji Sawa and Yukihiro Nishikawa and Hiroshi Jinnai and Taihyun Chang and Toshio Nishi",

year = "2006",

language = "English",

pages = "927",

note = "55th SPSJ Annual Meeting ; Conference date: 24-05-2006 Through 26-05-2006",

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TY - CONF

T1 - 3D observation of Hexagonally Perforated Layer (HPL) structure in block copolymer thin films

AU - Sawa, Koji

AU - Nishikawa, Yukihiro

AU - Jinnai, Hiroshi

AU - Chang, Taihyun

AU - Nishi, Toshio

PY - 2006

Y1 - 2006

N2 - Three-dimentional structure of poly(styrene-block-isoprene) (SI) diblock copolymer thin films was studied by means of transmission electron microtomography (TEMT). After annealing at 120°C, it was found that the SI thin film spin-coated on silicon wafer exhibited Hexagonally Perforated Layer (HPL) morphology with its lamellae highly oriented parallel to the substrate. The stacking sequences of HPL channels can be modeled as both AB-stacking and ABC-stacking patterns, as illustrated in Fig. 1. As a result of three-dimensional observation, we found that this sample formed ABC-stacking.

AB - Three-dimentional structure of poly(styrene-block-isoprene) (SI) diblock copolymer thin films was studied by means of transmission electron microtomography (TEMT). After annealing at 120°C, it was found that the SI thin film spin-coated on silicon wafer exhibited Hexagonally Perforated Layer (HPL) morphology with its lamellae highly oriented parallel to the substrate. The stacking sequences of HPL channels can be modeled as both AB-stacking and ABC-stacking patterns, as illustrated in Fig. 1. As a result of three-dimensional observation, we found that this sample formed ABC-stacking.

KW - Block copolymer

KW - Hexagonally Perforated Layer

KW - Thin films

KW - Transmission Electron Microtomography

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UR - http://www.scopus.com/inward/citedby.url?scp=33749655591&partnerID=8YFLogxK

M3 - Paper

AN - SCOPUS:33749655591

SP - 927

T2 - 55th SPSJ Annual Meeting

Y2 - 24 May 2006 through 26 May 2006

ER -

3D observation of Hexagonally Perforated Layer (HPL) structure in block copolymer thin films

Abstract

Conference

Keywords

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