3D observation of microphase-separated structures of ABC triblock copolymers

Takeshi Kaneko, Kazuya Suda, Yukihiro Nishikawa, Hiroshi Jinnai, Kotaro Sato, Masami Kamigaito, Toshinori Kato, Tomohiro Ono, Eiji Nakamura, Toshio Nishi

Research output: Contribution to conferencePaperpeer-review

Abstract

ABC triblock copolymers are known to exhibit wide variety of different types of morphologies compared with AB diblock copolymers. In the present study, a series of poly(styrene-block-isoprene-block-(methyl methacrylate)) and poly(styrene-block-(ethylene-alt-propylene)-block-(methyl methacrylate)) triblock copolymers were synthesized and their morphologies were extensively studied. In one of the triblock copolymers, a very complicated three-dimensional (3D) structure that looked like "knitting pattern" was observed (see Fig. 2 above). The 3D structures will be examined by transmission electron microtomography (TEMT) at the conference time.

Original languageEnglish
Pages687
Number of pages1
Publication statusPublished - 2005
Event54th SPSJ Annual Meeting 2005 - Yokohama, Japan
Duration: 2005 May 252005 May 27

Conference

Conference54th SPSJ Annual Meeting 2005
Country/TerritoryJapan
CityYokohama
Period05/5/2505/5/27

Keywords

  • Knitting Pattern
  • Microphase-separated Structure
  • Transmission Electron Microtomography
  • Triblock copolymer

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