A cubic dipole lattice of water molecules trapped inside carbon cages

Shinobu Aoyagi; Norihisa Hoshino; Tomoyuki Akutagawa; Yuki Sado; Ryo Kitaura; Hisanori Shinohara; Kunihisa Sugimoto; Rui Zhang; Yasujiro Murata

doi:10.1039/c3cc46683c

A cubic dipole lattice of water molecules trapped inside carbon cages

Shinobu Aoyagi, Norihisa Hoshino, Tomoyuki Akutagawa, Yuki Sado, Ryo Kitaura, Hisanori Shinohara, Kunihisa Sugimoto, Rui Zhang, Yasujiro Murata

IMRAM - Materials-Measurement Hybrid Research Center

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

We report the crystal structure and dielectric properties of a pure H₂O@C₆₀ crystal at low temperature. The caged water molecules free from the hydrogen bonds rotate even at 8 K. The antifreeze rotating water molecules respond to an external electric field due to their permanent dipole moment.

Original language	English
Pages (from-to)	524-526
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	5
DOIs	https://doi.org/10.1039/c3cc46683c
Publication status	Published - 2014 Dec 10

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abstract = "We report the crystal structure and dielectric properties of a pure H2O@C60 crystal at low temperature. The caged water molecules free from the hydrogen bonds rotate even at 8 K. The antifreeze rotating water molecules respond to an external electric field due to their permanent dipole moment.",

author = "Shinobu Aoyagi and Norihisa Hoshino and Tomoyuki Akutagawa and Yuki Sado and Ryo Kitaura and Hisanori Shinohara and Kunihisa Sugimoto and Rui Zhang and Yasujiro Murata",

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AU - Aoyagi, Shinobu

AU - Hoshino, Norihisa

AU - Akutagawa, Tomoyuki

AU - Sado, Yuki

AU - Kitaura, Ryo

AU - Shinohara, Hisanori

AU - Sugimoto, Kunihisa

AU - Zhang, Rui

AU - Murata, Yasujiro

PY - 2014/12/10

Y1 - 2014/12/10

N2 - We report the crystal structure and dielectric properties of a pure H2O@C60 crystal at low temperature. The caged water molecules free from the hydrogen bonds rotate even at 8 K. The antifreeze rotating water molecules respond to an external electric field due to their permanent dipole moment.

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JO - Chemical Communications

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A cubic dipole lattice of water molecules trapped inside carbon cages

Abstract

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