TY - JOUR
T1 - A dimeric manganese(III) tetradentate Schiff base complex as a single-molecule magnet
AU - Miyasaka, Hitoshi
AU - Clérac, Rodolphe
AU - Wernsdorfer, Wolfgang
AU - Lecren, Lollita
AU - Bonhomme, Claire
AU - Sugiura, Ken Ichi
AU - Yamashita, Masahiro
PY - 2004/5/17
Y1 - 2004/5/17
N2 - Slow relaxation of the magnetization reveals the single-molecule magnetic behavior of [Mn2(saltmen)2(ReO4)2] (saltmen2- = N,N′-(1,1,2,2-tetramethylethylene) bis(salicylideneiminate), a simple, out-of-plane MnIII dimeric complex containing a [MnIII(μ-O)2MnIII] core (see structure shown, Mn brown, O red, N blue, Re pink). The two anisotropic MnIII ions are ferromagnetically coupled, which induces an S T = 4 ground state.
AB - Slow relaxation of the magnetization reveals the single-molecule magnetic behavior of [Mn2(saltmen)2(ReO4)2] (saltmen2- = N,N′-(1,1,2,2-tetramethylethylene) bis(salicylideneiminate), a simple, out-of-plane MnIII dimeric complex containing a [MnIII(μ-O)2MnIII] core (see structure shown, Mn brown, O red, N blue, Re pink). The two anisotropic MnIII ions are ferromagnetically coupled, which induces an S T = 4 ground state.
KW - Magnetic properties
KW - Manganese
KW - Quantum tunneling
KW - Schiff bases
KW - Single-molecule magnets
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U2 - 10.1002/anie.200353563
DO - 10.1002/anie.200353563
M3 - Article
C2 - 15150753
AN - SCOPUS:4544246820
SN - 1433-7851
VL - 43
SP - 2801
EP - 2805
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 21
ER -