A molecular probe for recognizing the size of hydrophobic cavities based on near-infrared absorbing diradical-PtII complexes

Kousaku Tamura; Atsuko Masuya; Nobuhiko Iki

doi:10.1039/c3cc41468j

A molecular probe for recognizing the size of hydrophobic cavities based on near-infrared absorbing diradical-Pt^II complexes

Kousaku Tamura, Atsuko Masuya, Nobuhiko Iki

ENV - Frontier Science for Advanced Environment

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A diradical-platinum(ii) complex was able to recognize the subtle difference in cavity size between β- and γ-cyclodextrin with on-off switching of intense near-infrared absorption. This provides a new probe for identifying the size of hydrophobic cavities, which has been successfully applied here to differentiate human serum albumin from α-chymotrypsin.

Original language	English
Pages (from-to)	4812-4814
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	42
DOIs	https://doi.org/10.1039/c3cc41468j
Publication status	Published - 2013 Apr 30

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c3cc41468j

Cite this

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title = "A molecular probe for recognizing the size of hydrophobic cavities based on near-infrared absorbing diradical-PtII complexes",

abstract = "A diradical-platinum(ii) complex was able to recognize the subtle difference in cavity size between β- and γ-cyclodextrin with on-off switching of intense near-infrared absorption. This provides a new probe for identifying the size of hydrophobic cavities, which has been successfully applied here to differentiate human serum albumin from α-chymotrypsin.",

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AU - Masuya, Atsuko

AU - Iki, Nobuhiko

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Y1 - 2013/4/30

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AB - A diradical-platinum(ii) complex was able to recognize the subtle difference in cavity size between β- and γ-cyclodextrin with on-off switching of intense near-infrared absorption. This provides a new probe for identifying the size of hydrophobic cavities, which has been successfully applied here to differentiate human serum albumin from α-chymotrypsin.

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A molecular probe for recognizing the size of hydrophobic cavities based on near-infrared absorbing diradical-Pt^II complexes

Abstract

ASJC Scopus subject areas

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