A new convenient method for the synthesis of mixed-ligand β-diketonato Tc(III) complexes

A. Mutalib; T. Sekine; T. Omori; K. Yoshihara

doi:10.1007/BF02039724

A new convenient method for the synthesis of mixed-ligand β-diketonato Tc(III) complexes

A. Mutalib, T. Sekine, T. Omori, K. Yoshihara

Division of Developmental Research in Education Programs

Research output: Contribution to journal › Article › peer-review

Abstract

A new convenient method has been proposed to synthesize mixed-ligand β-diketonato Tc(III) complexes, using the ligand exchange reaction [Tc(acac)₂(CH₃CN)₂]⁺+L^-→[Tc(acac)₂L]+ +2CH₃CN where L is bza, dpm or dbm. The yield was about 30-40%. UV-visible and IR spectra of these complexes were measured. Characteristic features of the compounds were compared with those of the corresponding complexes of ruthenium.

Original language	English
Pages (from-to)	311-318
Number of pages	8
Journal	Journal of Radioanalytical and Nuclear Chemistry Articles
Volume	178
Issue number	2
DOIs	https://doi.org/10.1007/BF02039724
Publication status	Published - 1994 Mar 1

ASJC Scopus subject areas

Analytical Chemistry
Nuclear Energy and Engineering
Radiology Nuclear Medicine and imaging
Pollution
Spectroscopy
Public Health, Environmental and Occupational Health
Health, Toxicology and Mutagenesis

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This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1007/BF02039724

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abstract = "A new convenient method has been proposed to synthesize mixed-ligand β-diketonato Tc(III) complexes, using the ligand exchange reaction [Tc(acac)2(CH3CN)2]++L-→[Tc(acac)2L]+ +2CH3CN where L is bza, dpm or dbm. The yield was about 30-40%. UV-visible and IR spectra of these complexes were measured. Characteristic features of the compounds were compared with those of the corresponding complexes of ruthenium.",

author = "A. Mutalib and T. Sekine and T. Omori and K. Yoshihara",

year = "1994",

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doi = "10.1007/BF02039724",

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T1 - A new convenient method for the synthesis of mixed-ligand β-diketonato Tc(III) complexes

AU - Mutalib, A.

AU - Sekine, T.

AU - Omori, T.

AU - Yoshihara, K.

PY - 1994/3/1

Y1 - 1994/3/1

N2 - A new convenient method has been proposed to synthesize mixed-ligand β-diketonato Tc(III) complexes, using the ligand exchange reaction [Tc(acac)2(CH3CN)2]++L-→[Tc(acac)2L]+ +2CH3CN where L is bza, dpm or dbm. The yield was about 30-40%. UV-visible and IR spectra of these complexes were measured. Characteristic features of the compounds were compared with those of the corresponding complexes of ruthenium.

AB - A new convenient method has been proposed to synthesize mixed-ligand β-diketonato Tc(III) complexes, using the ligand exchange reaction [Tc(acac)2(CH3CN)2]++L-→[Tc(acac)2L]+ +2CH3CN where L is bza, dpm or dbm. The yield was about 30-40%. UV-visible and IR spectra of these complexes were measured. Characteristic features of the compounds were compared with those of the corresponding complexes of ruthenium.

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JO - Journal of Radioanalytical and Nuclear Chemistry

JF - Journal of Radioanalytical and Nuclear Chemistry

IS - 2

ER -

A new convenient method for the synthesis of mixed-ligand β-diketonato Tc(III) complexes

Abstract

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