A new metal-metal bonded diruthenium(II,III) compound bridged by the dianionic tridentate ligand N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate (5-Clsalpy2-)

H. Miyasaka; C. Kachi-Terajima; T. Ishii; M. Yamashita

doi:10.1039/b103186b

A new metal-metal bonded diruthenium(II,III) compound bridged by the dianionic tridentate ligand N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate (5-Clsalpy^2-)

H. Miyasaka, C. Kachi-Terajima, T. Ishii, M. Yamashita

Advanced Institute for Materials Research (AIMR)

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The ligand-substitution reaction of Ru₂ (O₂CCH₃)₄Cl with the tridentate ligand N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate dianion (5-Clsalpy ^2-) led to the unique diruthenium(II,III) compound [{Na(THF)₂}{Ru₂-(O₂ CCH₃)₂(5-Clsalpy)₂}]·THF (1·THF) which revealed the characteristic 1-D chain structure of the repeating unit [-Na-O-Ru-Ru-O-]∞ and rich redox chemistry.

Original language	English
Pages (from-to)	1929-1930
Number of pages	2
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	13
DOIs	https://doi.org/10.1039/b103186b
Publication status	Published - 2001 Jan 1

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1039/b103186b

Cite this

@article{eb4cdbec193b479ebb2edf1cfaece42d,

title = "A new metal-metal bonded diruthenium(II,III) compound bridged by the dianionic tridentate ligand N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate (5-Clsalpy2-)",

abstract = "The ligand-substitution reaction of Ru2 (O2CCH3)4Cl with the tridentate ligand N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate dianion (5-Clsalpy 2-) led to the unique diruthenium(II,III) compound [{Na(THF)2}{Ru2-(O2 CCH3)2(5-Clsalpy)2}]·THF (1·THF) which revealed the characteristic 1-D chain structure of the repeating unit [-Na-O-Ru-Ru-O-]∞ and rich redox chemistry.",

author = "H. Miyasaka and C. Kachi-Terajima and T. Ishii and M. Yamashita",

year = "2001",

month = jan,

day = "1",

doi = "10.1039/b103186b",

language = "English",

pages = "1929--1930",

journal = "Dalton Transactions",

issn = "1472-7773",

publisher = "Royal Society of Chemistry",

number = "13",

}

TY - JOUR

T1 - A new metal-metal bonded diruthenium(II,III) compound bridged by the dianionic tridentate ligand N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate (5-Clsalpy2-)

AU - Miyasaka, H.

AU - Kachi-Terajima, C.

AU - Ishii, T.

AU - Yamashita, M.

PY - 2001/1/1

Y1 - 2001/1/1

N2 - The ligand-substitution reaction of Ru2 (O2CCH3)4Cl with the tridentate ligand N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate dianion (5-Clsalpy 2-) led to the unique diruthenium(II,III) compound [{Na(THF)2}{Ru2-(O2 CCH3)2(5-Clsalpy)2}]·THF (1·THF) which revealed the characteristic 1-D chain structure of the repeating unit [-Na-O-Ru-Ru-O-]∞ and rich redox chemistry.

AB - The ligand-substitution reaction of Ru2 (O2CCH3)4Cl with the tridentate ligand N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate dianion (5-Clsalpy 2-) led to the unique diruthenium(II,III) compound [{Na(THF)2}{Ru2-(O2 CCH3)2(5-Clsalpy)2}]·THF (1·THF) which revealed the characteristic 1-D chain structure of the repeating unit [-Na-O-Ru-Ru-O-]∞ and rich redox chemistry.

UR - http://www.scopus.com/inward/record.url?scp=0034742952&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0034742952&partnerID=8YFLogxK

U2 - 10.1039/b103186b

DO - 10.1039/b103186b

M3 - Article

AN - SCOPUS:0034742952

SN - 1472-7773

SP - 1929

EP - 1930

JO - Dalton Transactions

JF - Dalton Transactions

IS - 13

ER -

A new metal-metal bonded diruthenium(II,III) compound bridged by the dianionic tridentate ligand N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate (5-Clsalpy^2-)

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this