A new ring expansion for a chiral hexahydroazulene skeleton possessing an angular methyl group

Masaatsu Adachi; Takema Komada; Toshio Nishikawa

doi:10.1021/jo201153h

A new ring expansion for a chiral hexahydroazulene skeleton possessing an angular methyl group

Masaatsu Adachi, Takema Komada, Toshio Nishikawa

PHA - Molecular Pharmaceutical Science

Nagoya University

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

A new synthetic route for a pseudoguaiane ring system is described. The synthesis features an Ireland-Claisen rearrangement for constructing the trans-fused ring system, followed by a new ring expansion to yield a bicyclo[5.3.0]decane ring system possessing an angular methyl group.

Original language	English
Pages (from-to)	6942-6945
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	76
Issue number	16
DOIs	https://doi.org/10.1021/jo201153h
Publication status	Published - 2011 Aug 19

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10.1021/jo201153h

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title = "A new ring expansion for a chiral hexahydroazulene skeleton possessing an angular methyl group",

abstract = "A new synthetic route for a pseudoguaiane ring system is described. The synthesis features an Ireland-Claisen rearrangement for constructing the trans-fused ring system, followed by a new ring expansion to yield a bicyclo[5.3.0]decane ring system possessing an angular methyl group.",

author = "Masaatsu Adachi and Takema Komada and Toshio Nishikawa",

year = "2011",

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doi = "10.1021/jo201153h",

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journal = "Journal of Organic Chemistry",

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AU - Adachi, Masaatsu

AU - Komada, Takema

AU - Nishikawa, Toshio

PY - 2011/8/19

Y1 - 2011/8/19

N2 - A new synthetic route for a pseudoguaiane ring system is described. The synthesis features an Ireland-Claisen rearrangement for constructing the trans-fused ring system, followed by a new ring expansion to yield a bicyclo[5.3.0]decane ring system possessing an angular methyl group.

AB - A new synthetic route for a pseudoguaiane ring system is described. The synthesis features an Ireland-Claisen rearrangement for constructing the trans-fused ring system, followed by a new ring expansion to yield a bicyclo[5.3.0]decane ring system possessing an angular methyl group.

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 16

ER -

A new ring expansion for a chiral hexahydroazulene skeleton possessing an angular methyl group

Abstract

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