A new route to carbon film coating by anodic electrodeposition from ionic liquid containing different phenylsilane derivatives

Nana Hozuki; Hidetaka Takato; Shingo Maruyama; Michio Kondo; Kenjiro Fujimoto; Yuji Matsumoto

doi:10.1246/CL.200537

A new route to carbon film coating by anodic electrodeposition from ionic liquid containing different phenylsilane derivatives

Nana Hozuki, Hidetaka Takato, Shingo Maruyama, Michio Kondo, Kenjiro Fujimoto, Yuji Matsumoto

ENG - Applied Chemistry

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

We propose a new direct anodic electrodeposition process for carbon coatings that is possible at room temperature in ionic liquid (IL) with phenylsilane derivatives, which include dimethylphenylsilane (DMPh-Si), methyldiphenylsilane (MDPh-Si), and triphenylsilane (TriPh-Si). Amongst them, MDPh-Si was found to most efficiently result in the electrodeposition of graphite carbon films even within the electrochemical window of IL. Electrochemical redox performance of Li⁺/Li couple on the obtained carbon film electrodes is also discussed.

Original language	English
Pages (from-to)	1349-1352
Number of pages	4
Journal	Chemistry Letters
Volume	49
Issue number	11
DOIs	https://doi.org/10.1246/CL.200537
Publication status	Published - 2020 Nov

Keywords

Carbon films
Electrodeposition
Ionic liquid

ASJC Scopus subject areas

Chemistry(all)

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10.1246/CL.200537

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title = "A new route to carbon film coating by anodic electrodeposition from ionic liquid containing different phenylsilane derivatives",

abstract = "We propose a new direct anodic electrodeposition process for carbon coatings that is possible at room temperature in ionic liquid (IL) with phenylsilane derivatives, which include dimethylphenylsilane (DMPh-Si), methyldiphenylsilane (MDPh-Si), and triphenylsilane (TriPh-Si). Amongst them, MDPh-Si was found to most efficiently result in the electrodeposition of graphite carbon films even within the electrochemical window of IL. Electrochemical redox performance of Li+/Li couple on the obtained carbon film electrodes is also discussed.",

keywords = "Carbon films, Electrodeposition, Ionic liquid",

author = "Nana Hozuki and Hidetaka Takato and Shingo Maruyama and Michio Kondo and Kenjiro Fujimoto and Yuji Matsumoto",

note = "Publisher Copyright: {\textcopyright} 2020 The Chemical Society of Japan",

year = "2020",

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doi = "10.1246/CL.200537",

language = "English",

volume = "49",

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TY - JOUR

T1 - A new route to carbon film coating by anodic electrodeposition from ionic liquid containing different phenylsilane derivatives

AU - Hozuki, Nana

AU - Takato, Hidetaka

AU - Maruyama, Shingo

AU - Kondo, Michio

AU - Fujimoto, Kenjiro

AU - Matsumoto, Yuji

PY - 2020/11

Y1 - 2020/11

N2 - We propose a new direct anodic electrodeposition process for carbon coatings that is possible at room temperature in ionic liquid (IL) with phenylsilane derivatives, which include dimethylphenylsilane (DMPh-Si), methyldiphenylsilane (MDPh-Si), and triphenylsilane (TriPh-Si). Amongst them, MDPh-Si was found to most efficiently result in the electrodeposition of graphite carbon films even within the electrochemical window of IL. Electrochemical redox performance of Li+/Li couple on the obtained carbon film electrodes is also discussed.

AB - We propose a new direct anodic electrodeposition process for carbon coatings that is possible at room temperature in ionic liquid (IL) with phenylsilane derivatives, which include dimethylphenylsilane (DMPh-Si), methyldiphenylsilane (MDPh-Si), and triphenylsilane (TriPh-Si). Amongst them, MDPh-Si was found to most efficiently result in the electrodeposition of graphite carbon films even within the electrochemical window of IL. Electrochemical redox performance of Li+/Li couple on the obtained carbon film electrodes is also discussed.

KW - Carbon films

KW - Electrodeposition

KW - Ionic liquid

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M3 - Article

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SN - 0366-7022

VL - 49

SP - 1349

EP - 1352

JO - Chemistry Letters

JF - Chemistry Letters

IS - 11

ER -

A new route to carbon film coating by anodic electrodeposition from ionic liquid containing different phenylsilane derivatives

Abstract

Keywords

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