A novel method of direct synthesis of dimethyl carbonate from methanol and carbon dioxide catalyzed by zirconia

Keiichi Tomishige; Tomohiro Sakaihori; Yoshiki Ikeda; Kaoru Fujimoto

doi:10.1023/A:1019098405444

A novel method of direct synthesis of dimethyl carbonate from methanol and carbon dioxide catalyzed by zirconia

Keiichi Tomishige, Tomohiro Sakaihori, Yoshiki Ikeda, Kaoru Fujimoto

ENG - Applied Chemistry

The University of Tokyo

Research output: Contribution to journal › Article › peer-review

262 Citations (Scopus)

Abstract

Dimethyl carbonate was synthesized from methanol and CO₂ with high selectivity using ZrO₂ catalysts. In this reaction, the amount of dimethyl ether and CO was below the detection limit. The catalytic activity seems to be related to acid-base pair sites of the ZrO₂ surface from the results of temperature-programmed desorption of NH₃ and CO₂.

Original language	English
Pages (from-to)	225-229
Number of pages	5
Journal	Catalysis Letters
Volume	58
Issue number	4
DOIs	https://doi.org/10.1023/A:1019098405444
Publication status	Published - 1999 Apr

Keywords

Dimethyl carbonate
DMC synthesis from CO
Zirconia

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10.1023/A:1019098405444

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title = "A novel method of direct synthesis of dimethyl carbonate from methanol and carbon dioxide catalyzed by zirconia",

abstract = "Dimethyl carbonate was synthesized from methanol and CO2 with high selectivity using ZrO2 catalysts. In this reaction, the amount of dimethyl ether and CO was below the detection limit. The catalytic activity seems to be related to acid-base pair sites of the ZrO2 surface from the results of temperature-programmed desorption of NH3 and CO2.",

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author = "Keiichi Tomishige and Tomohiro Sakaihori and Yoshiki Ikeda and Kaoru Fujimoto",

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AU - Tomishige, Keiichi

AU - Sakaihori, Tomohiro

AU - Ikeda, Yoshiki

AU - Fujimoto, Kaoru

PY - 1999/4

Y1 - 1999/4

N2 - Dimethyl carbonate was synthesized from methanol and CO2 with high selectivity using ZrO2 catalysts. In this reaction, the amount of dimethyl ether and CO was below the detection limit. The catalytic activity seems to be related to acid-base pair sites of the ZrO2 surface from the results of temperature-programmed desorption of NH3 and CO2.

AB - Dimethyl carbonate was synthesized from methanol and CO2 with high selectivity using ZrO2 catalysts. In this reaction, the amount of dimethyl ether and CO was below the detection limit. The catalytic activity seems to be related to acid-base pair sites of the ZrO2 surface from the results of temperature-programmed desorption of NH3 and CO2.

KW - Dimethyl carbonate

KW - DMC synthesis from CO

KW - Zirconia

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JF - Catalysis Letters

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ER -

A novel method of direct synthesis of dimethyl carbonate from methanol and carbon dioxide catalyzed by zirconia

Abstract

Keywords

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