A p-tert-butyldithiacalix[4]arene-copper(II) complex having double-cone shape of unique heteroditopic inclusion behavior

Noriyoshi Kon; Nobuhiko Iki; Takashi Kajiwara; Tasuku Ito; Sotaro Miyano

doi:10.1246/cl.2004.1046

A p-tert-butyldithiacalix[4]arene-copper(II) complex having double-cone shape of unique heteroditopic inclusion behavior

Noriyoshi Kon, Nobuhiko Iki, Takashi Kajiwara, Tasuku Ito, Sotaro Miyano

ENV - Frontier Science for Advanced Environment

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

X-ray diffraction revealed a single crystal of a Cu(II) complex of p-tert-butyldithiacalix[4]arene 5 (H₄L) to be [Cu₃(HL)- (H₂L)(AcO)], in which three Cu(II) ions are sandwiched by two calixarene ligands including different guest molecules, CHCl₃ and hexane, in each cone-shaped cavity.

Original language	English
Pages (from-to)	1046-1047
Number of pages	2
Journal	Chemistry Letters
Volume	33
Issue number	8
DOIs	https://doi.org/10.1246/cl.2004.1046
Publication status	Published - 2004 Aug 5

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2004.1046

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abstract = "X-ray diffraction revealed a single crystal of a Cu(II) complex of p-tert-butyldithiacalix[4]arene 5 (H4L) to be [Cu3(HL)- (H2L)(AcO)], in which three Cu(II) ions are sandwiched by two calixarene ligands including different guest molecules, CHCl3 and hexane, in each cone-shaped cavity.",

author = "Noriyoshi Kon and Nobuhiko Iki and Takashi Kajiwara and Tasuku Ito and Sotaro Miyano",

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AU - Iki, Nobuhiko

AU - Kajiwara, Takashi

AU - Ito, Tasuku

AU - Miyano, Sotaro

PY - 2004/8/5

Y1 - 2004/8/5

N2 - X-ray diffraction revealed a single crystal of a Cu(II) complex of p-tert-butyldithiacalix[4]arene 5 (H4L) to be [Cu3(HL)- (H2L)(AcO)], in which three Cu(II) ions are sandwiched by two calixarene ligands including different guest molecules, CHCl3 and hexane, in each cone-shaped cavity.

AB - X-ray diffraction revealed a single crystal of a Cu(II) complex of p-tert-butyldithiacalix[4]arene 5 (H4L) to be [Cu3(HL)- (H2L)(AcO)], in which three Cu(II) ions are sandwiched by two calixarene ligands including different guest molecules, CHCl3 and hexane, in each cone-shaped cavity.

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A p-tert-butyldithiacalix[4]arene-copper(II) complex having double-cone shape of unique heteroditopic inclusion behavior

Abstract

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