A perspective on mechanoluminescence and multipiezo in ferroelectric materials

The discovery of innovative mechanoluminescence materials of SrAl₂O₄ and ZnS, which emit repeatable light [repeatable mechanoluminescence (ML), hereafter simply ML] even by soft touch, has trigged intense research interest in material/device/system development for applications across various fields. This perspective presents an overview of the crystal structures, mechanisms, and ML behaviors of most promising systems, namely, SrAl₂O₄-, ZnS-, LiNbO₃-, and Sr₃Sn₂O₇-based ferroelectric materials. These multipiezo materials, which simultaneously exhibit intrinsic piezoluminescence (true elastic deformation induced ML and no friction effect) and piezoelectricity, show distinct and valuable characteristics by integrating mechanical force, electric field, and light for stress sensing and other applications. Recent studies indicated the critical role of crystal structure, doping, and piezoelectric properties in achieving robust and reliable ML performance. These findings suggest that ML materials hold substantial promise for applications in stress/force sensing, structural health monitoring, mechanically activated lighting, and advanced imaging techniques. Further investigation and advancement of multipiezo materials could yield breakthroughs, further augmenting their usefulness across various industries and scientific domains. Exploring ferroelectric ML materials offer new prospects for developing advanced materials with unique electro-mechano-optical properties.