A preliminary step toward molecular spring driven by cooperative guest binding

Tomohiro Ikeda, Seiji Shinkai, Kazuki Sada, Masayuki Takeuchi

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

A macrocyclic host molecule that comprised two different rotating modules, cerium(IV) bis(porphyrinate)s and ferrocenyl rotating units, exhibiting contraction/expansion motion was synthesized, which can be regarded as a prototype of artificial molecular spring driven by cooperative guest binding in 1:6 stoichiometry.

Original languageEnglish
Pages (from-to)2006-2009
Number of pages4
JournalTetrahedron Letters
Volume50
Issue number17
DOIs
Publication statusPublished - 2009 Apr 29

Keywords

  • Allosterism
  • Molecular machinery
  • Molecular recognition
  • Porphyrinoids

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