A supramolecular cation in an electrically conducting nickel dithiolate salt

Tomoyuki Akutagawa; Takayoshi Nakamura; Tamotsu Inabe; Allan E. Underhill

doi:10.1039/a607600k

A supramolecular cation in an electrically conducting nickel dithiolate salt

Tomoyuki Akutagawa, Takayoshi Nakamura, Tamotsu Inabe, Allan E. Underhill

IMRAM - Materials-Measurement Hybrid Research Center

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

A novel dimeric penta-coordinated ion cavity of [Li⁺]₂[12-crown-4-ether]₃ has been formed in the highly conducting Ni(dmit)₂ salt. This salt showed a room-temperature conductivity of 30 S cm^-1 and exhibited a semiconductor-semiconductor phase transition on the application of pressure or on lowering the temperature.

Original language	English
Pages (from-to)	183-185
Number of pages	3
Journal	Journal of Materials Chemistry
Volume	7
Issue number	2
DOIs	https://doi.org/10.1039/a607600k
Publication status	Published - 1997 Feb

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title = "A supramolecular cation in an electrically conducting nickel dithiolate salt",

abstract = "A novel dimeric penta-coordinated ion cavity of [Li+]2[12-crown-4-ether]3 has been formed in the highly conducting Ni(dmit)2 salt. This salt showed a room-temperature conductivity of 30 S cm-1 and exhibited a semiconductor-semiconductor phase transition on the application of pressure or on lowering the temperature.",

author = "Tomoyuki Akutagawa and Takayoshi Nakamura and Tamotsu Inabe and Underhill, {Allan E.}",

year = "1997",

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AB - A novel dimeric penta-coordinated ion cavity of [Li+]2[12-crown-4-ether]3 has been formed in the highly conducting Ni(dmit)2 salt. This salt showed a room-temperature conductivity of 30 S cm-1 and exhibited a semiconductor-semiconductor phase transition on the application of pressure or on lowering the temperature.

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A supramolecular cation in an electrically conducting nickel dithiolate salt

Abstract

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