Adsorption of propylene carbonate (PC) on the LiCoO2 surface investigated by nonlinear vibrational spectroscopy

Huijin Liu; Yujin Tong; Naoaki Kuwata; Masatoshi Osawa; Junichi Kawamura; Shen Ye

doi:10.1021/jp907146n

Adsorption of propylene carbonate (PC) on the LiCoO₂ surface investigated by nonlinear vibrational spectroscopy

Huijin Liu, Yujin Tong, Naoaki Kuwata, Masatoshi Osawa, Junichi Kawamura, Shen Ye

Research output: Contribution to journal › Article › peer-review

53 Citations (Scopus)

Abstract

The adsorption of propylene carbonate (PC) on the surface of the LiCoO ₂ thin-film, one of the important cathode materials used in the lithium-ion (Li-ion) battery, has been investigated by in situ sum frequency generation vibrational spectroscopy. Two adsorption modes of PC molecules with opposite orientation geometries on the LiCoO₂ surface have been observed. The adsorption structures of PC are affected by the solvation process of the Li⁺ ion.

Original language	English
Pages (from-to)	20531-20534
Number of pages	4
Journal	Journal of Physical Chemistry C
Volume	113
Issue number	48
DOIs	https://doi.org/10.1021/jp907146n
Publication status	Published - 2009

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abstract = "The adsorption of propylene carbonate (PC) on the surface of the LiCoO 2 thin-film, one of the important cathode materials used in the lithium-ion (Li-ion) battery, has been investigated by in situ sum frequency generation vibrational spectroscopy. Two adsorption modes of PC molecules with opposite orientation geometries on the LiCoO2 surface have been observed. The adsorption structures of PC are affected by the solvation process of the Li+ ion.",

author = "Huijin Liu and Yujin Tong and Naoaki Kuwata and Masatoshi Osawa and Junichi Kawamura and Shen Ye",

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AU - Liu, Huijin

AU - Tong, Yujin

AU - Kuwata, Naoaki

AU - Osawa, Masatoshi

AU - Kawamura, Junichi

AU - Ye, Shen

PY - 2009

Y1 - 2009

N2 - The adsorption of propylene carbonate (PC) on the surface of the LiCoO 2 thin-film, one of the important cathode materials used in the lithium-ion (Li-ion) battery, has been investigated by in situ sum frequency generation vibrational spectroscopy. Two adsorption modes of PC molecules with opposite orientation geometries on the LiCoO2 surface have been observed. The adsorption structures of PC are affected by the solvation process of the Li+ ion.

AB - The adsorption of propylene carbonate (PC) on the surface of the LiCoO 2 thin-film, one of the important cathode materials used in the lithium-ion (Li-ion) battery, has been investigated by in situ sum frequency generation vibrational spectroscopy. Two adsorption modes of PC molecules with opposite orientation geometries on the LiCoO2 surface have been observed. The adsorption structures of PC are affected by the solvation process of the Li+ ion.

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ER -

Adsorption of propylene carbonate (PC) on the LiCoO₂ surface investigated by nonlinear vibrational spectroscopy

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