Allosteric silver(I) ion binding with peripheral π clefts of a ce(IV) double decker porphyrin

Masato Ikeda; Tomoyuki Tanida; Masayuki Takeuchi; Seiji Shinkai

doi:10.1021/ol005807a

Allosteric silver(I) ion binding with peripheral π clefts of a ce(IV) double decker porphyrin

Masato Ikeda, Tomoyuki Tanida, Masayuki Takeuchi, Seiji Shinkai

IMRAM - Materials-Measurement Hybrid Research Center

Kyushu University

Research output: Contribution to journal › Article › peer-review

67 Citations (Scopus)

Abstract

(Formula presented) A cerium(IV) double decker porphyrin (1) bearing four 4-methoxyphenyl groups was synthesized. Compound 1 shows a positive, homotoropic allosteric effect in metal recognition of Ag⁺ ion, and the peripheral π clefts of 1 act as effective binding sites for Ag⁺ ion.

Original language	English
Pages (from-to)	1803-1805
Number of pages	3
Journal	Organic Letters
Volume	2
Issue number	13
DOIs	https://doi.org/10.1021/ol005807a
Publication status	Published - 2000 Jun 29

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10.1021/ol005807a

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title = "Allosteric silver(I) ion binding with peripheral π clefts of a ce(IV) double decker porphyrin",

abstract = "(Formula presented) A cerium(IV) double decker porphyrin (1) bearing four 4-methoxyphenyl groups was synthesized. Compound 1 shows a positive, homotoropic allosteric effect in metal recognition of Ag+ ion, and the peripheral π clefts of 1 act as effective binding sites for Ag+ ion.",

author = "Masato Ikeda and Tomoyuki Tanida and Masayuki Takeuchi and Seiji Shinkai",

year = "2000",

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T1 - Allosteric silver(I) ion binding with peripheral π clefts of a ce(IV) double decker porphyrin

AU - Ikeda, Masato

AU - Tanida, Tomoyuki

AU - Takeuchi, Masayuki

AU - Shinkai, Seiji

PY - 2000/6/29

Y1 - 2000/6/29

N2 - (Formula presented) A cerium(IV) double decker porphyrin (1) bearing four 4-methoxyphenyl groups was synthesized. Compound 1 shows a positive, homotoropic allosteric effect in metal recognition of Ag+ ion, and the peripheral π clefts of 1 act as effective binding sites for Ag+ ion.

AB - (Formula presented) A cerium(IV) double decker porphyrin (1) bearing four 4-methoxyphenyl groups was synthesized. Compound 1 shows a positive, homotoropic allosteric effect in metal recognition of Ag+ ion, and the peripheral π clefts of 1 act as effective binding sites for Ag+ ion.

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ER -

Allosteric silver(I) ion binding with peripheral π clefts of a ce(IV) double decker porphyrin

Abstract

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