Amination of alcohols with ammonia in water over Rhin catalyst

Tsukasa Takanashi; Yoshinao Nakagawa; Keiichi Tomishige

doi:10.1246/cl.140051

Amination of alcohols with ammonia in water over Rhin catalyst

Tsukasa Takanashi, Yoshinao Nakagawa, Keiichi Tomishige

ENG - Applied Chemistry

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Amination of various C3 alcohols such as 1,2-propanediol with ammonia was catalyzed by RhIn/C in water while Rh/C was totally inactive. Activated carbon FAC-10 was the best support in terms of activity and resistance to metal leaching. In the amination of 1,2-propanediol, RhIn/C produced amino alcohols in 68% total selectivity and 38% conversion. XRD and TEM measurements showed that RhIn alloy particle with size of 34 nm was formed on the carbon support.

Original language	English
Pages (from-to)	822-824
Number of pages	3
Journal	Chemistry Letters
Volume	43
Issue number	6
DOIs	https://doi.org/10.1246/cl.140051
Publication status	Published - 2014

ASJC Scopus subject areas

Chemistry(all)

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abstract = "Amination of various C3 alcohols such as 1,2-propanediol with ammonia was catalyzed by RhIn/C in water while Rh/C was totally inactive. Activated carbon FAC-10 was the best support in terms of activity and resistance to metal leaching. In the amination of 1,2-propanediol, RhIn/C produced amino alcohols in 68% total selectivity and 38% conversion. XRD and TEM measurements showed that RhIn alloy particle with size of 34 nm was formed on the carbon support.",

author = "Tsukasa Takanashi and Yoshinao Nakagawa and Keiichi Tomishige",

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AU - Takanashi, Tsukasa

AU - Nakagawa, Yoshinao

AU - Tomishige, Keiichi

PY - 2014

Y1 - 2014

N2 - Amination of various C3 alcohols such as 1,2-propanediol with ammonia was catalyzed by RhIn/C in water while Rh/C was totally inactive. Activated carbon FAC-10 was the best support in terms of activity and resistance to metal leaching. In the amination of 1,2-propanediol, RhIn/C produced amino alcohols in 68% total selectivity and 38% conversion. XRD and TEM measurements showed that RhIn alloy particle with size of 34 nm was formed on the carbon support.

AB - Amination of various C3 alcohols such as 1,2-propanediol with ammonia was catalyzed by RhIn/C in water while Rh/C was totally inactive. Activated carbon FAC-10 was the best support in terms of activity and resistance to metal leaching. In the amination of 1,2-propanediol, RhIn/C produced amino alcohols in 68% total selectivity and 38% conversion. XRD and TEM measurements showed that RhIn alloy particle with size of 34 nm was formed on the carbon support.

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ER -

Amination of alcohols with ammonia in water over Rhin catalyst

Abstract

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