Amorphous water in three-dimensional confinement of zeolite-templated carbon

Haruka Kyakuno; Kazuyuki Matsuda; Yusuke Nakai; Tomoko Fukuoka; Yutaka Maniwa; Hirotomo Nishihara; Takashi Kyotani

doi:10.1016/j.cplett.2013.04.016

Amorphous water in three-dimensional confinement of zeolite-templated carbon

Haruka Kyakuno, Kazuyuki Matsuda, Yusuke Nakai, Tomoko Fukuoka, Yutaka Maniwa, Hirotomo Nishihara, Takashi Kyotani

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

A newly developed nano-structural material, zeolite-templated carbon (ZTC), adsorbs a large amount of water, up to 120-170 wt.% with respect to the dry ZTC. Here, we investigated this nanoconfined water by several experimental methods, including specific heat and nuclear magnetic resonance measurements, and molecular dynamics simulations. The water was highly mobile down to 200 K and its rotational correlation time followed an apparent non-Arrhenius behavior. With decreasing temperature, it was suggested that the water freezes into a low-density amorphous ice with a possible glass transition temperature of around 150 K. ZTC provides a new platform to study three-dimensional 'supercooled' water.

Original language	English
Pages (from-to)	54-60
Number of pages	7
Journal	Chemical Physics Letters
Volume	571
DOIs	https://doi.org/10.1016/j.cplett.2013.04.016
Publication status	Published - 2013 May 20

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

Access to Document

10.1016/j.cplett.2013.04.016

Cite this

@article{3fa387a84a264524a458e68965bd7f0f,

title = "Amorphous water in three-dimensional confinement of zeolite-templated carbon",

abstract = "A newly developed nano-structural material, zeolite-templated carbon (ZTC), adsorbs a large amount of water, up to 120-170 wt.% with respect to the dry ZTC. Here, we investigated this nanoconfined water by several experimental methods, including specific heat and nuclear magnetic resonance measurements, and molecular dynamics simulations. The water was highly mobile down to 200 K and its rotational correlation time followed an apparent non-Arrhenius behavior. With decreasing temperature, it was suggested that the water freezes into a low-density amorphous ice with a possible glass transition temperature of around 150 K. ZTC provides a new platform to study three-dimensional 'supercooled' water.",

author = "Haruka Kyakuno and Kazuyuki Matsuda and Yusuke Nakai and Tomoko Fukuoka and Yutaka Maniwa and Hirotomo Nishihara and Takashi Kyotani",

note = "Funding Information: This work was in parts supported by a Grant-in-Aid for Scientific Research on Priority Area {\textquoteleft}New Materials Science Using Regulated Nano Spaces{\textquoteright}, and by JSPS KAKENHI Grant Number 21540421.",

year = "2013",

month = may,

day = "20",

doi = "10.1016/j.cplett.2013.04.016",

language = "English",

volume = "571",

pages = "54--60",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier",

}

TY - JOUR

T1 - Amorphous water in three-dimensional confinement of zeolite-templated carbon

AU - Kyakuno, Haruka

AU - Matsuda, Kazuyuki

AU - Nakai, Yusuke

AU - Fukuoka, Tomoko

AU - Maniwa, Yutaka

AU - Nishihara, Hirotomo

AU - Kyotani, Takashi

N1 - Funding Information: This work was in parts supported by a Grant-in-Aid for Scientific Research on Priority Area ‘New Materials Science Using Regulated Nano Spaces’, and by JSPS KAKENHI Grant Number 21540421.

PY - 2013/5/20

Y1 - 2013/5/20

N2 - A newly developed nano-structural material, zeolite-templated carbon (ZTC), adsorbs a large amount of water, up to 120-170 wt.% with respect to the dry ZTC. Here, we investigated this nanoconfined water by several experimental methods, including specific heat and nuclear magnetic resonance measurements, and molecular dynamics simulations. The water was highly mobile down to 200 K and its rotational correlation time followed an apparent non-Arrhenius behavior. With decreasing temperature, it was suggested that the water freezes into a low-density amorphous ice with a possible glass transition temperature of around 150 K. ZTC provides a new platform to study three-dimensional 'supercooled' water.

AB - A newly developed nano-structural material, zeolite-templated carbon (ZTC), adsorbs a large amount of water, up to 120-170 wt.% with respect to the dry ZTC. Here, we investigated this nanoconfined water by several experimental methods, including specific heat and nuclear magnetic resonance measurements, and molecular dynamics simulations. The water was highly mobile down to 200 K and its rotational correlation time followed an apparent non-Arrhenius behavior. With decreasing temperature, it was suggested that the water freezes into a low-density amorphous ice with a possible glass transition temperature of around 150 K. ZTC provides a new platform to study three-dimensional 'supercooled' water.

UR - http://www.scopus.com/inward/record.url?scp=84877794062&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84877794062&partnerID=8YFLogxK

U2 - 10.1016/j.cplett.2013.04.016

DO - 10.1016/j.cplett.2013.04.016

M3 - Article

AN - SCOPUS:84877794062

SN - 0009-2614

VL - 571

SP - 54

EP - 60

JO - Chemical Physics Letters

JF - Chemical Physics Letters

ER -

Amorphous water in three-dimensional confinement of zeolite-templated carbon

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this