An enantio- and stereo-controlled synthesis of L-erythro- and D-threo-C18-sphingosines via the anomalous version of the katsuki-sharpless asymmetric epoxidation reaction

Seiichi Takano; Yoshiharu Iwabuchi; Kunio Ogasawara

doi:10.1039/C39910000820

An enantio- and stereo-controlled synthesis of L-erythro- and D-threo-C₁₈-sphingosines via the anomalous version of the katsuki-sharpless asymmetric epoxidation reaction

Seiichi Takano, Yoshiharu Iwabuchi, Kunio Ogasawara

PHA - Molecular Pharmaceutical Science

Tohoku University

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

A new enantiocontrolled synthesis of L-erythro- and D-threo-sphingosines has been established starting from (R,R)- and meso-1,2-divinylethylene glycols via the anomalous version of the Katsuki-Sharpless asymmetric epoxidation reaction as the key step.

Original language	English
Pages (from-to)	820-821
Number of pages	2
Journal	Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/C39910000820
Publication status	Published - 1991

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10.1039/C39910000820

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abstract = "A new enantiocontrolled synthesis of L-erythro- and D-threo-sphingosines has been established starting from (R,R)- and meso-1,2-divinylethylene glycols via the anomalous version of the Katsuki-Sharpless asymmetric epoxidation reaction as the key step.",

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AU - Iwabuchi, Yoshiharu

AU - Ogasawara, Kunio

PY - 1991

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AB - A new enantiocontrolled synthesis of L-erythro- and D-threo-sphingosines has been established starting from (R,R)- and meso-1,2-divinylethylene glycols via the anomalous version of the Katsuki-Sharpless asymmetric epoxidation reaction as the key step.

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An enantio- and stereo-controlled synthesis of L-erythro- and D-threo-C₁₈-sphingosines via the anomalous version of the katsuki-sharpless asymmetric epoxidation reaction

Abstract

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