An Extremely Air-Stable 19π Porphyrinoid

Takuya Yoshida; Wen Zhou; Taniyuki Furuyama; Daniel B. Leznoff; Nagao Kobayashi

doi:10.1021/jacs.5b05781

An Extremely Air-Stable 19π Porphyrinoid

Takuya Yoshida, Wen Zhou, Taniyuki Furuyama, Daniel B. Leznoff, Nagao Kobayashi

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

A one-electron reduced species of a cationic phosphorus(V) tetraazaporphyrin complex has been isolated as an air-stable solid. Cyclic voltammetry and magnetic measurements showed the species to be a neutral π radical, and the solid state structure was elucidated by single crystal X-ray diffraction analysis. Magnetic circular dichroism spectroscopy and theoretical calculations also support a 19π electron conjugated electronic circuit.

Original language	English
Pages (from-to)	9258-9261
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	137
Issue number	29
DOIs	https://doi.org/10.1021/jacs.5b05781
Publication status	Published - 2015 Jul 29
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/jacs.5b05781

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author = "Takuya Yoshida and Wen Zhou and Taniyuki Furuyama and Leznoff, {Daniel B.} and Nagao Kobayashi",

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AU - Leznoff, Daniel B.

AU - Kobayashi, Nagao

PY - 2015/7/29

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AB - A one-electron reduced species of a cationic phosphorus(V) tetraazaporphyrin complex has been isolated as an air-stable solid. Cyclic voltammetry and magnetic measurements showed the species to be a neutral π radical, and the solid state structure was elucidated by single crystal X-ray diffraction analysis. Magnetic circular dichroism spectroscopy and theoretical calculations also support a 19π electron conjugated electronic circuit.

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An Extremely Air-Stable 19π Porphyrinoid

Abstract

ASJC Scopus subject areas

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