Anhydrous proton conductivity of a lamella-structured inorganic-organic zirconium-monododecyl phosphate crystalline hybrid

Je Deok Kim; Toshiyuki Mori; Itaru Honma

doi:10.1016/j.jpowsour.2007.05.031

Anhydrous proton conductivity of a lamella-structured inorganic-organic zirconium-monododecyl phosphate crystalline hybrid

Je Deok Kim, Toshiyuki Mori, Itaru Honma

IMRAM - Center for Mineral Processing and Metallurgy (CMPM)

National Institute for Materials Science Tsukuba

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

A lamella-structured inorganic-organic zirconium-monododecyl phosphate crystalline hybrid was investigated as an anhydrous proton conductor. Inorganic zirconium ions were coordinated by OH groups of a phosphate moiety from organic monododecyl phosphate. The inorganic-organic zirconium-monododecyl phosphate hybrid showed a lamella structure with crystalline ZrP, and the thermal stability increased up to 230 °C. A maximum proton conductivity of 2 × 10^-3 S cm^-1 was obtained at 150 °C under anhydrous conditions. The high proton conductivity under high temperature and anhydrous conditions could be explained by considering the interaction between Zr ions and the phosphate group, and the phosphate concentration in the lamella-structured inorganic-organic zirconium-monododecyl phosphate hybrid.

Original language	English
Pages (from-to)	694-697
Number of pages	4
Journal	Journal of Power Sources
Volume	172
Issue number	2
DOIs	https://doi.org/10.1016/j.jpowsour.2007.05.031
Publication status	Published - 2007 Oct 25

Keywords

Anhydrous proton conductor
High-temperature PEFC
Inorganic-organic hybrid
Zirconium-monododecyl phosphate hybrid

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.jpowsour.2007.05.031

Cite this

@article{acb3fd49c8c24503b9b8f96e9c537f84,

title = "Anhydrous proton conductivity of a lamella-structured inorganic-organic zirconium-monododecyl phosphate crystalline hybrid",

abstract = "A lamella-structured inorganic-organic zirconium-monododecyl phosphate crystalline hybrid was investigated as an anhydrous proton conductor. Inorganic zirconium ions were coordinated by OH groups of a phosphate moiety from organic monododecyl phosphate. The inorganic-organic zirconium-monododecyl phosphate hybrid showed a lamella structure with crystalline ZrP, and the thermal stability increased up to 230 °C. A maximum proton conductivity of 2 × 10-3 S cm-1 was obtained at 150 °C under anhydrous conditions. The high proton conductivity under high temperature and anhydrous conditions could be explained by considering the interaction between Zr ions and the phosphate group, and the phosphate concentration in the lamella-structured inorganic-organic zirconium-monododecyl phosphate hybrid.",

keywords = "Anhydrous proton conductor, High-temperature PEFC, Inorganic-organic hybrid, Zirconium-monododecyl phosphate hybrid",

author = "Kim, {Je Deok} and Toshiyuki Mori and Itaru Honma",

year = "2007",

month = oct,

day = "25",

doi = "10.1016/j.jpowsour.2007.05.031",

language = "English",

volume = "172",

pages = "694--697",

journal = "Journal of Power Sources",

issn = "0378-7753",

publisher = "Elsevier",

number = "2",

}

TY - JOUR

T1 - Anhydrous proton conductivity of a lamella-structured inorganic-organic zirconium-monododecyl phosphate crystalline hybrid

AU - Kim, Je Deok

AU - Mori, Toshiyuki

AU - Honma, Itaru

PY - 2007/10/25

Y1 - 2007/10/25

N2 - A lamella-structured inorganic-organic zirconium-monododecyl phosphate crystalline hybrid was investigated as an anhydrous proton conductor. Inorganic zirconium ions were coordinated by OH groups of a phosphate moiety from organic monododecyl phosphate. The inorganic-organic zirconium-monododecyl phosphate hybrid showed a lamella structure with crystalline ZrP, and the thermal stability increased up to 230 °C. A maximum proton conductivity of 2 × 10-3 S cm-1 was obtained at 150 °C under anhydrous conditions. The high proton conductivity under high temperature and anhydrous conditions could be explained by considering the interaction between Zr ions and the phosphate group, and the phosphate concentration in the lamella-structured inorganic-organic zirconium-monododecyl phosphate hybrid.

AB - A lamella-structured inorganic-organic zirconium-monododecyl phosphate crystalline hybrid was investigated as an anhydrous proton conductor. Inorganic zirconium ions were coordinated by OH groups of a phosphate moiety from organic monododecyl phosphate. The inorganic-organic zirconium-monododecyl phosphate hybrid showed a lamella structure with crystalline ZrP, and the thermal stability increased up to 230 °C. A maximum proton conductivity of 2 × 10-3 S cm-1 was obtained at 150 °C under anhydrous conditions. The high proton conductivity under high temperature and anhydrous conditions could be explained by considering the interaction between Zr ions and the phosphate group, and the phosphate concentration in the lamella-structured inorganic-organic zirconium-monododecyl phosphate hybrid.

KW - Anhydrous proton conductor

KW - High-temperature PEFC

KW - Inorganic-organic hybrid

KW - Zirconium-monododecyl phosphate hybrid

UR - http://www.scopus.com/inward/record.url?scp=34748894340&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34748894340&partnerID=8YFLogxK

U2 - 10.1016/j.jpowsour.2007.05.031

DO - 10.1016/j.jpowsour.2007.05.031

M3 - Article

AN - SCOPUS:34748894340

SN - 0378-7753

VL - 172

SP - 694

EP - 697

JO - Journal of Power Sources

JF - Journal of Power Sources

IS - 2

ER -

Anhydrous proton conductivity of a lamella-structured inorganic-organic zirconium-monododecyl phosphate crystalline hybrid

Abstract

Keywords

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this