Anthryl-substituted trialkyldisilene showing distinct intramolecular charge-transfer transition

Takeaki Iwamoto; Maiko Kobayashi; Kei Uchiyama; Shin Sasaki; Selvarajan Nagendran; Hiroyuki Isobe; Mitsuo Kira

doi:10.1021/ja8093313

Anthryl-substituted trialkyldisilene showing distinct intramolecular charge-transfer transition

Takeaki Iwamoto, Maiko Kobayashi, Kei Uchiyama, Shin Sasaki, Selvarajan Nagendran, Hiroyuki Isobe, Mitsuo Kira

SCI - Chemistry

Tohoku University

Research output: Contribution to journal › Article › peer-review

80 Citations (Scopus)

Abstract

1-Naphthyl-, 9-phenanthryl-, and 9-anthryl-substituted trialkyldisilenes 1-3 were synthesized as the first stable disilenes with single polycyclic aromatic substituents, allowing elucidation of the unprecedented intramolecular charge transfer interaction between disilene π and aromatic π systems. Anthryl-substituted disilene 3 having a low-lying π^*LUMO showed a distinct ICT absorption band due to the charge transfer from a disilene π donor to an aromatic π acceptor.

Original language	English
Pages (from-to)	3156-3157
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	9
DOIs	https://doi.org/10.1021/ja8093313
Publication status	Published - 2009 Mar 11

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abstract = "1-Naphthyl-, 9-phenanthryl-, and 9-anthryl-substituted trialkyldisilenes 1-3 were synthesized as the first stable disilenes with single polycyclic aromatic substituents, allowing elucidation of the unprecedented intramolecular charge transfer interaction between disilene π and aromatic π systems. Anthryl-substituted disilene 3 having a low-lying π*LUMO showed a distinct ICT absorption band due to the charge transfer from a disilene π donor to an aromatic π acceptor.",

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T1 - Anthryl-substituted trialkyldisilene showing distinct intramolecular charge-transfer transition

AU - Iwamoto, Takeaki

AU - Kobayashi, Maiko

AU - Uchiyama, Kei

AU - Sasaki, Shin

AU - Nagendran, Selvarajan

AU - Isobe, Hiroyuki

AU - Kira, Mitsuo

PY - 2009/3/11

Y1 - 2009/3/11

N2 - 1-Naphthyl-, 9-phenanthryl-, and 9-anthryl-substituted trialkyldisilenes 1-3 were synthesized as the first stable disilenes with single polycyclic aromatic substituents, allowing elucidation of the unprecedented intramolecular charge transfer interaction between disilene π and aromatic π systems. Anthryl-substituted disilene 3 having a low-lying π*LUMO showed a distinct ICT absorption band due to the charge transfer from a disilene π donor to an aromatic π acceptor.

AB - 1-Naphthyl-, 9-phenanthryl-, and 9-anthryl-substituted trialkyldisilenes 1-3 were synthesized as the first stable disilenes with single polycyclic aromatic substituents, allowing elucidation of the unprecedented intramolecular charge transfer interaction between disilene π and aromatic π systems. Anthryl-substituted disilene 3 having a low-lying π*LUMO showed a distinct ICT absorption band due to the charge transfer from a disilene π donor to an aromatic π acceptor.

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 9

ER -

Anthryl-substituted trialkyldisilene showing distinct intramolecular charge-transfer transition

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