Aryl iodides as strong inhibitors in gold and gold-based bimetallic quasi-homogeneous catalysis

Raghu Nath Dhital; Choavarit Kamonsatikul; Ekasith Somsook; Yoshinori Sato; Hidehiro Sakurai

doi:10.1039/c3cc39019e

Aryl iodides as strong inhibitors in gold and gold-based bimetallic quasi-homogeneous catalysis

Raghu Nath Dhital, Choavarit Kamonsatikul, Ekasith Somsook, Yoshinori Sato, Hidehiro Sakurai

ENV - Environmental Studies for Advanced Society

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

The strong inhibitor effect of aryl iodides on the quasi-homogenous gold-catalyzed oxidation reaction was described. Aryl iodides were adsorbed on the exposed surface of Au clusters, which affected the accessibility of the nanoclusters to the reacting species and acted as strong inhibitors in catalysis.

Original language	English
Pages (from-to)	2542-2544
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	25
DOIs	https://doi.org/10.1039/c3cc39019e
Publication status	Published - 2013 Feb 28

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title = "Aryl iodides as strong inhibitors in gold and gold-based bimetallic quasi-homogeneous catalysis",

abstract = "The strong inhibitor effect of aryl iodides on the quasi-homogenous gold-catalyzed oxidation reaction was described. Aryl iodides were adsorbed on the exposed surface of Au clusters, which affected the accessibility of the nanoclusters to the reacting species and acted as strong inhibitors in catalysis.",

author = "Dhital, {Raghu Nath} and Choavarit Kamonsatikul and Ekasith Somsook and Yoshinori Sato and Hidehiro Sakurai",

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AU - Dhital, Raghu Nath

AU - Kamonsatikul, Choavarit

AU - Somsook, Ekasith

AU - Sato, Yoshinori

AU - Sakurai, Hidehiro

PY - 2013/2/28

Y1 - 2013/2/28

N2 - The strong inhibitor effect of aryl iodides on the quasi-homogenous gold-catalyzed oxidation reaction was described. Aryl iodides were adsorbed on the exposed surface of Au clusters, which affected the accessibility of the nanoclusters to the reacting species and acted as strong inhibitors in catalysis.

AB - The strong inhibitor effect of aryl iodides on the quasi-homogenous gold-catalyzed oxidation reaction was described. Aryl iodides were adsorbed on the exposed surface of Au clusters, which affected the accessibility of the nanoclusters to the reacting species and acted as strong inhibitors in catalysis.

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DO - 10.1039/c3cc39019e

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VL - 49

SP - 2542

EP - 2544

JO - Chemical Communications

JF - Chemical Communications

IS - 25

ER -

Aryl iodides as strong inhibitors in gold and gold-based bimetallic quasi-homogeneous catalysis

Abstract

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