Asymmetric michael reaction of aldehyde and β-substituted α-nitroacrylate catalyzed by diphenylprolinol silyl ether

Daisuke Sakamoto; Yujiro Hayashi

doi:10.1246/cl.180273

Asymmetric michael reaction of aldehyde and β-substituted α-nitroacrylate catalyzed by diphenylprolinol silyl ether

Daisuke Sakamoto, Yujiro Hayashi

SCI - Chemistry

Tohoku University

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The asymmetric Michael reaction of an aldehyde and β-substituted α-nitroacrylate, catalyzed by diphenylprolinol silyl ether, was successfully carried out and good yield was achieved. This reaction has broad substrate generality. Moreover, the product can be easily converted to pyrrolidine or lactone.

Original language	English
Pages (from-to)	833-835
Number of pages	3
Journal	Chemistry Letters
Volume	47
Issue number	7
DOIs	https://doi.org/10.1246/cl.180273
Publication status	Published - 2018

Keywords

Asymmetric reaction
Michael reaction
Organocatalyst

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10.1246/cl.180273

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title = "Asymmetric michael reaction of aldehyde and β-substituted α-nitroacrylate catalyzed by diphenylprolinol silyl ether",

abstract = "The asymmetric Michael reaction of an aldehyde and β-substituted α-nitroacrylate, catalyzed by diphenylprolinol silyl ether, was successfully carried out and good yield was achieved. This reaction has broad substrate generality. Moreover, the product can be easily converted to pyrrolidine or lactone.",

keywords = "Asymmetric reaction, Michael reaction, Organocatalyst",

author = "Daisuke Sakamoto and Yujiro Hayashi",

note = "Publisher Copyright: {\textcopyright} 2018 The Chemical Society of Japan",

year = "2018",

doi = "10.1246/cl.180273",

language = "English",

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journal = "Chemistry Letters",

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AU - Sakamoto, Daisuke

AU - Hayashi, Yujiro

PY - 2018

Y1 - 2018

N2 - The asymmetric Michael reaction of an aldehyde and β-substituted α-nitroacrylate, catalyzed by diphenylprolinol silyl ether, was successfully carried out and good yield was achieved. This reaction has broad substrate generality. Moreover, the product can be easily converted to pyrrolidine or lactone.

AB - The asymmetric Michael reaction of an aldehyde and β-substituted α-nitroacrylate, catalyzed by diphenylprolinol silyl ether, was successfully carried out and good yield was achieved. This reaction has broad substrate generality. Moreover, the product can be easily converted to pyrrolidine or lactone.

KW - Asymmetric reaction

KW - Michael reaction

KW - Organocatalyst

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M3 - Article

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 7

ER -

Asymmetric michael reaction of aldehyde and β-substituted α-nitroacrylate catalyzed by diphenylprolinol silyl ether

Abstract

Keywords

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