Asymmetric Michael reaction of aldehydes and nitroalkenes

Yujiro Hayashi; Shin Ogasawara; Yasuyuki Ueda; Keisuke Suzuki

doi:10.1002/0471264229.os094.18

Asymmetric Michael reaction of aldehydes and nitroalkenes

Yujiro Hayashi, Shin Ogasawara, Yasuyuki Ueda, Keisuke Suzuki

SCI - Chemistry

Tohoku University

Research output: Contribution to journal › Article › peer-review

Abstract

A procedure yielding alcohol 2 as a yellow oil is presented. The main paraphernalia used is a three‐necked round‐bottomed flask equipped with an egg‐shaped, Teflon‐coated, magnetic stir bar, an internal thermometer, a two‐way stopcock with a hose, and a three‐way stopcock connected to a nitrogen inlet hose. A brief summary of asymmetric Michael reaction of aldehydes and nitroalkenes concludes the chapter.

Original language	English
Journal	Organic Syntheses
Volume	94
DOIs	https://doi.org/10.1002/0471264229.os094.18
Publication status	Published - 2018 Jun 20

Keywords

Aldehydes
Diastereoselectivity
Diphenylprolinol trimethylsilyl ether
Michael reaction
Nitroalkenes
Sodium borohydride

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10.1002/0471264229.os094.18

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title = "Asymmetric Michael reaction of aldehydes and nitroalkenes",

abstract = "A procedure yielding alcohol 2 as a yellow oil is presented. The main paraphernalia used is a three‐necked round‐bottomed flask equipped with an egg‐shaped, Teflon‐coated, magnetic stir bar, an internal thermometer, a two‐way stopcock with a hose, and a three‐way stopcock connected to a nitrogen inlet hose. A brief summary of asymmetric Michael reaction of aldehydes and nitroalkenes concludes the chapter.",

keywords = "Aldehydes, Diastereoselectivity, Diphenylprolinol trimethylsilyl ether, Michael reaction, Nitroalkenes, Sodium borohydride",

author = "Yujiro Hayashi and Shin Ogasawara and Yasuyuki Ueda and Keisuke Suzuki",

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doi = "10.1002/0471264229.os094.18",

language = "English",

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T1 - Asymmetric Michael reaction of aldehydes and nitroalkenes

AU - Hayashi, Yujiro

AU - Ogasawara, Shin

AU - Ueda, Yasuyuki

AU - Suzuki, Keisuke

PY - 2018/6/20

Y1 - 2018/6/20

N2 - A procedure yielding alcohol 2 as a yellow oil is presented. The main paraphernalia used is a three‐necked round‐bottomed flask equipped with an egg‐shaped, Teflon‐coated, magnetic stir bar, an internal thermometer, a two‐way stopcock with a hose, and a three‐way stopcock connected to a nitrogen inlet hose. A brief summary of asymmetric Michael reaction of aldehydes and nitroalkenes concludes the chapter.

AB - A procedure yielding alcohol 2 as a yellow oil is presented. The main paraphernalia used is a three‐necked round‐bottomed flask equipped with an egg‐shaped, Teflon‐coated, magnetic stir bar, an internal thermometer, a two‐way stopcock with a hose, and a three‐way stopcock connected to a nitrogen inlet hose. A brief summary of asymmetric Michael reaction of aldehydes and nitroalkenes concludes the chapter.

KW - Aldehydes

KW - Diastereoselectivity

KW - Diphenylprolinol trimethylsilyl ether

KW - Michael reaction

KW - Nitroalkenes

KW - Sodium borohydride

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SN - 0078-6209

VL - 94

JO - Organic Syntheses

JF - Organic Syntheses

ER -

Asymmetric Michael reaction of aldehydes and nitroalkenes

Abstract

Keywords

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