Asymmetric reduction of 3,5-dinitroacetophenone using CT complexation with optically active 1,12-dialkylbenzo[c]phenanthrenes

Hiroki Sugiura; Kazuhiro Teranishi; Ryo Amemiya; Masahiko Yamaguchi

doi:10.1246/cl.2008.158

Asymmetric reduction of 3,5-dinitroacetophenone using CT complexation with optically active 1,12-dialkylbenzo[c]phenanthrenes

Hiroki Sugiura, Kazuhiro Teranishi, Ryo Amemiya, Masahiko Yamaguchi

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Optically active 1,12-dialkylbenzo[c]phenanthrene-5,8-dimethanols and its derivatives formed charge-transfer (CT) complexes with 3,5-dinitroacetophenone in solution, and the treatment of the complexes with borohydrides provided the optically active alcohol up to 13% ee.

Original language	English
Pages (from-to)	158-159
Number of pages	2
Journal	Chemistry Letters
Volume	37
Issue number	2
DOIs	https://doi.org/10.1246/cl.2008.158
Publication status	Published - 2008 Feb 5
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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abstract = "Optically active 1,12-dialkylbenzo[c]phenanthrene-5,8-dimethanols and its derivatives formed charge-transfer (CT) complexes with 3,5-dinitroacetophenone in solution, and the treatment of the complexes with borohydrides provided the optically active alcohol up to 13% ee.",

author = "Hiroki Sugiura and Kazuhiro Teranishi and Ryo Amemiya and Masahiko Yamaguchi",

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AU - Sugiura, Hiroki

AU - Teranishi, Kazuhiro

AU - Amemiya, Ryo

AU - Yamaguchi, Masahiko

PY - 2008/2/5

Y1 - 2008/2/5

N2 - Optically active 1,12-dialkylbenzo[c]phenanthrene-5,8-dimethanols and its derivatives formed charge-transfer (CT) complexes with 3,5-dinitroacetophenone in solution, and the treatment of the complexes with borohydrides provided the optically active alcohol up to 13% ee.

AB - Optically active 1,12-dialkylbenzo[c]phenanthrene-5,8-dimethanols and its derivatives formed charge-transfer (CT) complexes with 3,5-dinitroacetophenone in solution, and the treatment of the complexes with borohydrides provided the optically active alcohol up to 13% ee.

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Asymmetric reduction of 3,5-dinitroacetophenone using CT complexation with optically active 1,12-dialkylbenzo[c]phenanthrenes

Abstract

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