Asymmetric synthesis of N-diphenylphosphinoylamines by solvent-free enantioselective addition of dialkylzincs to N-diphenylphosphinoylimines

Itaru Sato; Ryo Kodaka; Kenso Soai

doi:10.1039/b106775n

Asymmetric synthesis of N-diphenylphosphinoylamines by solvent-free enantioselective addition of dialkylzincs to N-diphenylphosphinoylimines

Itaru Sato, Ryo Kodaka, Kenso Soai

SCI - Research and Analytical Center for Giant Molecules

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

Solvent-free enantioselective addition of dialkylzincs to N-diphenylphosphinoylimines in the presence of chiral 2-morpholino-1-phenylpropan-1-ol affords N-diphenylphosphinoylamines with up to 97% ee. The reaction in the solvent-free system is faster than in organic solvents.

Original language	English
Pages (from-to)	2912-2914
Number of pages	3
Journal	Journal of the Chemical Society. Perkin Transactions 1
Volume	1
Issue number	22
DOIs	https://doi.org/10.1039/b106775n
Publication status	Published - 2001 Oct 15

ASJC Scopus subject areas

Chemistry(all)

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abstract = "Solvent-free enantioselective addition of dialkylzincs to N-diphenylphosphinoylimines in the presence of chiral 2-morpholino-1-phenylpropan-1-ol affords N-diphenylphosphinoylamines with up to 97% ee. The reaction in the solvent-free system is faster than in organic solvents.",

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Asymmetric synthesis of N-diphenylphosphinoylamines by solvent-free enantioselective addition of dialkylzincs to N-diphenylphosphinoylimines

Abstract

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