Atomic observation of catalysis-induced nanopore coarsening of nanoporous gold

Takeshi Fujita, Tomoharu Tokunaga, Ling Zhang, Dongwei Li, Luyang Chen, Shigeo Arai, Yuta Yamamoto, Akihiko Hirata, Nobuo Tanaka, Yi Ding, Mingwei Chen

Research output: Contribution to journalArticlepeer-review

102 Citations (Scopus)


Dealloyed nanoporous metals have attracted much attention because of their excellent catalytic activities toward various chemical reactions. Nevertheless, coarsening mechanisms in these catalysts have not been experimentally studied. Here, we report in situ atomic-scale observations of the structural evolution of nanoporous gold during catalytic CO oxidation. The catalysis-induced nanopore coarsening is associated with the rapid diffusion of gold atoms at chemically active surface steps and the surface segregation of residual Ag atoms, both of which are stimulated by the chemical reaction. Our observations provide the first direct evidence that planar defects hinder nanopore coarsening, suggesting a new strategy for developing structurally stable and highly active heterogeneous catalysts.

Original languageEnglish
Pages (from-to)1172-1177
Number of pages6
JournalNano Letters
Issue number3
Publication statusPublished - 2014 Mar 12


  • CO oxidation
  • In situ TEM
  • environmental transmission electron microscopy
  • heterogeneous catalyst
  • nanoporous metal

ASJC Scopus subject areas

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering


Dive into the research topics of 'Atomic observation of catalysis-induced nanopore coarsening of nanoporous gold'. Together they form a unique fingerprint.

Cite this