Abstract
In order to elucidate state-to-state dissociation dynamics of inner-shell photoexcited molecules, we have investigated ionic fragmentations by energy-resolved Auger-electron-photoion coincidence techniques. Results are presented for the fragmentation of SiF4 following the Si 2p photoionization. It is found that the fragmentation patterns strongly depend on the Auger final states. The dissociation pathways are discussed on the basis of comparison between the present results and the appearance potential of the ionic species and ion pairs in the literature.
Original language | English |
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Pages (from-to) | 495-498 |
Number of pages | 4 |
Journal | Journal of Electron Spectroscopy and Related Phenomena |
Volume | 79 |
DOIs | |
Publication status | Published - 1996 May |
Externally published | Yes |
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Radiation
- Atomic and Molecular Physics, and Optics
- Condensed Matter Physics
- Spectroscopy
- Physical and Theoretical Chemistry