TY - JOUR
T1 - Ba14Cu2In4N7, a new subnitride with isolated nitridocuprate groups and indium clusters
AU - Yamane, Hisanori
AU - Sasaki, Shinya
AU - Kubota, Shunichi
AU - Kajiwara, Takashi
AU - Shimada, Masahiko
PY - 2002/4
Y1 - 2002/4
N2 - Single crystals of Ba14Cu2In4N7, tetradecabarium dicopper tetraindium heptanitride, were synthesized by slow cooling from 1023 K at 7 MPa of N2 using an Na flux. The compound crystallizes in the monoclinic space group P2/m with Z = 2, and contains 0[CuN2] nitridocuprate units and distorted 0[In4] clusters. One Ba atom, not connected to any N atoms, is surrounded by 12 other Ba atoms in a barium cuboctahedron. The structural formula is expressed as (Ba)Ba27N6[CuN2]4[In4] 2.
AB - Single crystals of Ba14Cu2In4N7, tetradecabarium dicopper tetraindium heptanitride, were synthesized by slow cooling from 1023 K at 7 MPa of N2 using an Na flux. The compound crystallizes in the monoclinic space group P2/m with Z = 2, and contains 0[CuN2] nitridocuprate units and distorted 0[In4] clusters. One Ba atom, not connected to any N atoms, is surrounded by 12 other Ba atoms in a barium cuboctahedron. The structural formula is expressed as (Ba)Ba27N6[CuN2]4[In4] 2.
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U2 - 10.1107/S010827010200361X
DO - 10.1107/S010827010200361X
M3 - Article
C2 - 11932513
AN - SCOPUS:0036529024
SN - 0108-2701
VL - 58
SP - i50-i52
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 4
ER -