Binaphthol-Titanium Complex-Catalyzed Fluoral-Ene Reaction with Vinyl Sulfides for Asymmetric Synthesis of Diastereomeric α-Trifluoromethyl-β-methyl Carbinols: Diastereomer Switch of Antiferroelectric or Ferroelectric Properties of Diastereomeric Liquid-Crystalline Systems

Koichi Mikami; Tomoko Yajima; Nasakul Siree; Masahiro Terada; Yoshiichi Suzuki; Ichiro Kobayashi

doi:10.1055/s-1996-5630

Binaphthol-Titanium Complex-Catalyzed Fluoral-Ene Reaction with Vinyl Sulfides for Asymmetric Synthesis of Diastereomeric α-Trifluoromethyl-β-methyl Carbinols: Diastereomer Switch of Antiferroelectric or Ferroelectric Properties of Diastereomeric Liquid-Crystalline Systems

Koichi Mikami, Tomoko Yajima, Nasakul Siree, Masahiro Terada, Yoshiichi Suzuki, Ichiro Kobayashi

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

We synthesized a new type of antiferroelectric and ferroelectric liquid-crystalline molecules with double stereogenic centers based on the binaphthol-titanium complex-catalyzed fluoralene reaction with vinyl sulfides. Furthermore, we experimentally showed the importance of the diastereomer effect for the appearance of the antiferroelectric SmC_A* phase.

Original language	English
Pages (from-to)	837-838
Number of pages	2
Journal	Synlett
Volume	1996
Issue number	9
DOIs	https://doi.org/10.1055/s-1996-5630
Publication status	Published - 1996
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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Mikami, K., Yajima, T., Siree, N., Terada, M., Suzuki, Y., & Kobayashi, I. (1996). Binaphthol-Titanium Complex-Catalyzed Fluoral-Ene Reaction with Vinyl Sulfides for Asymmetric Synthesis of Diastereomeric α-Trifluoromethyl-β-methyl Carbinols: Diastereomer Switch of Antiferroelectric or Ferroelectric Properties of Diastereomeric Liquid-Crystalline Systems. Synlett, 1996(9), 837-838. https://doi.org/10.1055/s-1996-5630

Binaphthol-Titanium Complex-Catalyzed Fluoral-Ene Reaction with Vinyl Sulfides for Asymmetric Synthesis of Diastereomeric α-Trifluoromethyl-β-methyl Carbinols: Diastereomer Switch of Antiferroelectric or Ferroelectric Properties of Diastereomeric Liquid-Crystalline Systems. / Mikami, Koichi; Yajima, Tomoko; Siree, Nasakul et al.
In: Synlett, Vol. 1996, No. 9, 1996, p. 837-838.

Research output: Contribution to journal › Article › peer-review

Mikami, K, Yajima, T, Siree, N, Terada, M, Suzuki, Y & Kobayashi, I 1996, 'Binaphthol-Titanium Complex-Catalyzed Fluoral-Ene Reaction with Vinyl Sulfides for Asymmetric Synthesis of Diastereomeric α-Trifluoromethyl-β-methyl Carbinols: Diastereomer Switch of Antiferroelectric or Ferroelectric Properties of Diastereomeric Liquid-Crystalline Systems', Synlett, vol. 1996, no. 9, pp. 837-838. https://doi.org/10.1055/s-1996-5630

Mikami K, Yajima T, Siree N, Terada M, Suzuki Y, Kobayashi I. Binaphthol-Titanium Complex-Catalyzed Fluoral-Ene Reaction with Vinyl Sulfides for Asymmetric Synthesis of Diastereomeric α-Trifluoromethyl-β-methyl Carbinols: Diastereomer Switch of Antiferroelectric or Ferroelectric Properties of Diastereomeric Liquid-Crystalline Systems. Synlett. 1996;1996(9):837-838. doi: 10.1055/s-1996-5630

Mikami, Koichi ; Yajima, Tomoko ; Siree, Nasakul et al. / Binaphthol-Titanium Complex-Catalyzed Fluoral-Ene Reaction with Vinyl Sulfides for Asymmetric Synthesis of Diastereomeric α-Trifluoromethyl-β-methyl Carbinols : Diastereomer Switch of Antiferroelectric or Ferroelectric Properties of Diastereomeric Liquid-Crystalline Systems. In: Synlett. 1996 ; Vol. 1996, No. 9. pp. 837-838.

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abstract = "We synthesized a new type of antiferroelectric and ferroelectric liquid-crystalline molecules with double stereogenic centers based on the binaphthol-titanium complex-catalyzed fluoralene reaction with vinyl sulfides. Furthermore, we experimentally showed the importance of the diastereomer effect for the appearance of the antiferroelectric SmCA* phase.",

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Binaphthol-Titanium Complex-Catalyzed Fluoral-Ene Reaction with Vinyl Sulfides for Asymmetric Synthesis of Diastereomeric α-Trifluoromethyl-β-methyl Carbinols: Diastereomer Switch of Antiferroelectric or Ferroelectric Properties of Diastereomeric Liquid-Crystalline Systems

Abstract

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