Borylation on benzo[1,2- b:4,5- b ′]- and naphtho[1,2- b:5,6- b ′]dichalcogenophenes: Different chalcogene atom effects on borylation reaction depending on fused ring structure

Masahiro Nakano; Shoji Shinamura; Ryusuke Sugimoto; Itaru Osaka; Eigo Miyazaki; Kazuo Takimiya

doi:10.1021/ol302521d

Borylation on benzo[1,2- b:4,5- b ′]- and naphtho[1,2- b:5,6- b ′]dichalcogenophenes: Different chalcogene atom effects on borylation reaction depending on fused ring structure

Masahiro Nakano, Shoji Shinamura, Ryusuke Sugimoto, Itaru Osaka, Eigo Miyazaki, Kazuo Takimiya

SCI - Chemistry

Hiroshima University

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

The direct borylation reactions of two types of α-silyl-protected acenedichalcogenophenes, i.e., benzo[1,2-b:4,5-b′]- and naphtho[1,2-b:5,6-b′]dichalcogenophenes, were examined, and it was observed that the reaction efficiency largely depends on the fused ring structure and chalcogenophene ring.

Original language	English
Pages (from-to)	5448-5451
Number of pages	4
Journal	Organic Letters
Volume	14
Issue number	21
DOIs	https://doi.org/10.1021/ol302521d
Publication status	Published - 2012 Nov 2

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10.1021/ol302521d

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title = "Borylation on benzo[1,2- b:4,5- b ′]- and naphtho[1,2- b:5,6- b ′]dichalcogenophenes: Different chalcogene atom effects on borylation reaction depending on fused ring structure",

abstract = "The direct borylation reactions of two types of α-silyl-protected acenedichalcogenophenes, i.e., benzo[1,2-b:4,5-b′]- and naphtho[1,2-b:5,6-b′]dichalcogenophenes, were examined, and it was observed that the reaction efficiency largely depends on the fused ring structure and chalcogenophene ring.",

author = "Masahiro Nakano and Shoji Shinamura and Ryusuke Sugimoto and Itaru Osaka and Eigo Miyazaki and Kazuo Takimiya",

year = "2012",

month = nov,

day = "2",

doi = "10.1021/ol302521d",

language = "English",

volume = "14",

pages = "5448--5451",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "21",

}

Borylation on benzo[1,2- b:4,5- b ′]- and naphtho[1,2- b:5,6- b ′]dichalcogenophenes: Different chalcogene atom effects on borylation reaction depending on fused ring structure. / Nakano, Masahiro; Shinamura, Shoji; Sugimoto, Ryusuke et al.
In: Organic Letters, Vol. 14, No. 21, 02.11.2012, p. 5448-5451.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Borylation on benzo[1,2- b:4,5- b ′]- and naphtho[1,2- b:5,6- b ′]dichalcogenophenes

T2 - Different chalcogene atom effects on borylation reaction depending on fused ring structure

AU - Nakano, Masahiro

AU - Shinamura, Shoji

AU - Sugimoto, Ryusuke

AU - Osaka, Itaru

AU - Miyazaki, Eigo

AU - Takimiya, Kazuo

PY - 2012/11/2

Y1 - 2012/11/2

N2 - The direct borylation reactions of two types of α-silyl-protected acenedichalcogenophenes, i.e., benzo[1,2-b:4,5-b′]- and naphtho[1,2-b:5,6-b′]dichalcogenophenes, were examined, and it was observed that the reaction efficiency largely depends on the fused ring structure and chalcogenophene ring.

AB - The direct borylation reactions of two types of α-silyl-protected acenedichalcogenophenes, i.e., benzo[1,2-b:4,5-b′]- and naphtho[1,2-b:5,6-b′]dichalcogenophenes, were examined, and it was observed that the reaction efficiency largely depends on the fused ring structure and chalcogenophene ring.

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U2 - 10.1021/ol302521d

DO - 10.1021/ol302521d

M3 - Article

AN - SCOPUS:84868351299

SN - 1523-7060

VL - 14

SP - 5448

EP - 5451

JO - Organic Letters

JF - Organic Letters

IS - 21

ER -

Borylation on benzo[1,2- b:4,5- b ′]- and naphtho[1,2- b:5,6- b ′]dichalcogenophenes: Different chalcogene atom effects on borylation reaction depending on fused ring structure

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