Bottom-up fabrication of redox-active metal complex oligomer wires on an H-terminated Si(111) surface

Hiroaki Maeda; Ryota Sakamoto; Yoshihiko Nishimori; Junya Sendo; Fumiyuki Toshimitsu; Yoshinori Yamanoi; Hiroshi Nishihara

doi:10.1039/c1cc12832a

Bottom-up fabrication of redox-active metal complex oligomer wires on an H-terminated Si(111) surface

Hiroaki Maeda, Ryota Sakamoto, Yoshihiko Nishimori, Junya Sendo, Fumiyuki Toshimitsu, Yoshinori Yamanoi, Hiroshi Nishihara

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

Linear and branched Fe(tpy)₂ complex oligomer wires were quantitatively formed on hydrogen-terminated silicon wafers by means of hydrosilylation of ethynylterpyridine and following stepwise coordination reactions, and the redox property of surface-attached species and its photosensitivity can be controlled by the doping density of the silicon wafers.

Original language	English
Pages (from-to)	8644-8646
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	30
DOIs	https://doi.org/10.1039/c1cc12832a
Publication status	Published - 2011 Aug 14
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c1cc12832a

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abstract = "Linear and branched Fe(tpy)2 complex oligomer wires were quantitatively formed on hydrogen-terminated silicon wafers by means of hydrosilylation of ethynylterpyridine and following stepwise coordination reactions, and the redox property of surface-attached species and its photosensitivity can be controlled by the doping density of the silicon wafers.",

author = "Hiroaki Maeda and Ryota Sakamoto and Yoshihiko Nishimori and Junya Sendo and Fumiyuki Toshimitsu and Yoshinori Yamanoi and Hiroshi Nishihara",

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T1 - Bottom-up fabrication of redox-active metal complex oligomer wires on an H-terminated Si(111) surface

AU - Maeda, Hiroaki

AU - Sakamoto, Ryota

AU - Nishimori, Yoshihiko

AU - Sendo, Junya

AU - Toshimitsu, Fumiyuki

AU - Yamanoi, Yoshinori

AU - Nishihara, Hiroshi

PY - 2011/8/14

Y1 - 2011/8/14

N2 - Linear and branched Fe(tpy)2 complex oligomer wires were quantitatively formed on hydrogen-terminated silicon wafers by means of hydrosilylation of ethynylterpyridine and following stepwise coordination reactions, and the redox property of surface-attached species and its photosensitivity can be controlled by the doping density of the silicon wafers.

AB - Linear and branched Fe(tpy)2 complex oligomer wires were quantitatively formed on hydrogen-terminated silicon wafers by means of hydrosilylation of ethynylterpyridine and following stepwise coordination reactions, and the redox property of surface-attached species and its photosensitivity can be controlled by the doping density of the silicon wafers.

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U2 - 10.1039/c1cc12832a

DO - 10.1039/c1cc12832a

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JF - Chemical Communications

IS - 30

ER -

Bottom-up fabrication of redox-active metal complex oligomer wires on an H-terminated Si(111) surface

Abstract

ASJC Scopus subject areas

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