Catalytic materials for the hydrogenolysis of glycerol to 1,3-propanediol

Yoshinao Nakagawa; Masazumi Tamura; Keiichi Tomishige

doi:10.1039/c3ta15384c

Catalytic materials for the hydrogenolysis of glycerol to 1,3-propanediol

Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige

ENG - Applied Chemistry

Research output: Contribution to journal › Article › peer-review

154 Citations (Scopus)

Abstract

Recent progress in catalyst development for glycerol hydrogenolysis into 1,3-propanediol is reviewed. Unmodified conventional catalysts produce 1,2-propanediol as the main product instead of 1,3-propanediol. Most effective catalysts use noble metal as a center for hydrogen activation and tungsten or rhenium as an additive. Pt-WO₃ catalysts on Al-based supports and Ir-ReO_x/SiO₂ catalysts are especially effective in 1,3-propanediol production among the reported materials. Characterization results and proposed reaction mechanisms are also summarized.

Original language	English
Pages (from-to)	6688-6702
Number of pages	15
Journal	Journal of Materials Chemistry A
Volume	2
Issue number	19
DOIs	https://doi.org/10.1039/c3ta15384c
Publication status	Published - 2014 May 21

ASJC Scopus subject areas

Chemistry(all)
Renewable Energy, Sustainability and the Environment
Materials Science(all)

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This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1039/c3ta15384c

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abstract = "Recent progress in catalyst development for glycerol hydrogenolysis into 1,3-propanediol is reviewed. Unmodified conventional catalysts produce 1,2-propanediol as the main product instead of 1,3-propanediol. Most effective catalysts use noble metal as a center for hydrogen activation and tungsten or rhenium as an additive. Pt-WO3 catalysts on Al-based supports and Ir-ReOx/SiO2 catalysts are especially effective in 1,3-propanediol production among the reported materials. Characterization results and proposed reaction mechanisms are also summarized.",

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AU - Nakagawa, Yoshinao

AU - Tamura, Masazumi

AU - Tomishige, Keiichi

PY - 2014/5/21

Y1 - 2014/5/21

N2 - Recent progress in catalyst development for glycerol hydrogenolysis into 1,3-propanediol is reviewed. Unmodified conventional catalysts produce 1,2-propanediol as the main product instead of 1,3-propanediol. Most effective catalysts use noble metal as a center for hydrogen activation and tungsten or rhenium as an additive. Pt-WO3 catalysts on Al-based supports and Ir-ReOx/SiO2 catalysts are especially effective in 1,3-propanediol production among the reported materials. Characterization results and proposed reaction mechanisms are also summarized.

AB - Recent progress in catalyst development for glycerol hydrogenolysis into 1,3-propanediol is reviewed. Unmodified conventional catalysts produce 1,2-propanediol as the main product instead of 1,3-propanediol. Most effective catalysts use noble metal as a center for hydrogen activation and tungsten or rhenium as an additive. Pt-WO3 catalysts on Al-based supports and Ir-ReOx/SiO2 catalysts are especially effective in 1,3-propanediol production among the reported materials. Characterization results and proposed reaction mechanisms are also summarized.

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Catalytic materials for the hydrogenolysis of glycerol to 1,3-propanediol

Abstract

ASJC Scopus subject areas

UN SDGs

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