Catalytic oxidation of silyl enol ethers to 1,2-diketones employing nitroxyl radicals

Masaki Hayashi; Masatoshi Shibuya; Yoshiharu Iwabuchi

doi:10.1055/s-0031-1290528

Catalytic oxidation of silyl enol ethers to 1,2-diketones employing nitroxyl radicals

Masaki Hayashi, Masatoshi Shibuya, Yoshiharu Iwabuchi

PHA - Molecular Pharmaceutical Science

Research output: Contribution to journal › Review article › peer-review

31 Citations (Scopus)

Abstract

A novel and efficient method for the preparation of 1,2-diketones is reported. A series of -diketones were readily prepared by the nitroxyl-radical-catalyzed oxidation of silyl enol ethers using magnesium monoperoxyphthalate hexahydrate (MMPP6H) as the co-oxidant.

Original language	English
Pages (from-to)	1025-1030
Number of pages	6
Journal	Synlett
Volume	23
Issue number	7
DOIs	https://doi.org/10.1055/s-0031-1290528
Publication status	Published - 2012

Keywords

catalysis
diketones
enols
nitroxyl radical
oxidation

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10.1055/s-0031-1290528

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title = "Catalytic oxidation of silyl enol ethers to 1,2-diketones employing nitroxyl radicals",

abstract = "A novel and efficient method for the preparation of 1,2-diketones is reported. A series of -diketones were readily prepared by the nitroxyl-radical-catalyzed oxidation of silyl enol ethers using magnesium monoperoxyphthalate hexahydrate (MMPP6H) as the co-oxidant.",

keywords = "catalysis, diketones, enols, nitroxyl radical, oxidation",

author = "Masaki Hayashi and Masatoshi Shibuya and Yoshiharu Iwabuchi",

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T1 - Catalytic oxidation of silyl enol ethers to 1,2-diketones employing nitroxyl radicals

AU - Hayashi, Masaki

AU - Shibuya, Masatoshi

AU - Iwabuchi, Yoshiharu

PY - 2012

Y1 - 2012

N2 - A novel and efficient method for the preparation of 1,2-diketones is reported. A series of -diketones were readily prepared by the nitroxyl-radical-catalyzed oxidation of silyl enol ethers using magnesium monoperoxyphthalate hexahydrate (MMPP6H) as the co-oxidant.

AB - A novel and efficient method for the preparation of 1,2-diketones is reported. A series of -diketones were readily prepared by the nitroxyl-radical-catalyzed oxidation of silyl enol ethers using magnesium monoperoxyphthalate hexahydrate (MMPP6H) as the co-oxidant.

KW - catalysis

KW - diketones

KW - enols

KW - nitroxyl radical

KW - oxidation

UR - http://www.scopus.com/inward/record.url?scp=84859811974&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84859811974&partnerID=8YFLogxK

U2 - 10.1055/s-0031-1290528

DO - 10.1055/s-0031-1290528

M3 - Review article

AN - SCOPUS:84859811974

SN - 0936-5214

VL - 23

SP - 1025

EP - 1030

JO - Synlett

JF - Synlett

IS - 7

ER -

Catalytic oxidation of silyl enol ethers to 1,2-diketones employing nitroxyl radicals

Abstract

Keywords

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