TY - JOUR
T1 - Catalytic synthesis of unsaturated nitriles from NO-alkane or NO-alkene on Pt-Sn/SiO2
AU - Inoue, Tomoya
AU - Tomishige, Keiichi
AU - Iwasawa, Yasuhiro
PY - 1995
Y1 - 1995
N2 - The Pt-Sn/SiO2 catalysts prepared by selective bimetallic CVD reaction of SnMe4 with Pt particles on SiO2, characterized by EXAFS (extended X-ray absorption fine structure), yield acrylonitrile from NO + propene and methacrylonitrile from NO + isobutene and NO + isobutane with good selectivities, typically 70-93%, in contrast to negligible activity and selectivity (about one order of magnitude lower) with the monometallic Pt/SiO2 catalyst.
AB - The Pt-Sn/SiO2 catalysts prepared by selective bimetallic CVD reaction of SnMe4 with Pt particles on SiO2, characterized by EXAFS (extended X-ray absorption fine structure), yield acrylonitrile from NO + propene and methacrylonitrile from NO + isobutene and NO + isobutane with good selectivities, typically 70-93%, in contrast to negligible activity and selectivity (about one order of magnitude lower) with the monometallic Pt/SiO2 catalyst.
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U2 - 10.1039/C39950000329
DO - 10.1039/C39950000329
M3 - Article
AN - SCOPUS:37049081679
SN - 0022-4936
SP - 329
EP - 330
JO - Chemical Communications
JF - Chemical Communications
IS - 3
ER -