CeO2-ZrO2 solid solution catalyst for selective synthesis of dimethyl carbonate from methanol and carbon dioxide

Keiichi Tomishige; Yutaka Furusawa; Yoshiki Ikeda; Mohammad Asadullah; Kaoru Fujimoto

doi:10.1023/A:1016711722721

CeO₂-ZrO₂ solid solution catalyst for selective synthesis of dimethyl carbonate from methanol and carbon dioxide

Keiichi Tomishige, Yutaka Furusawa, Yoshiki Ikeda, Mohammad Asadullah, Kaoru Fujimoto

ENG - Applied Chemistry

The University of Tokyo

Research output: Contribution to journal › Article › peer-review

159 Citations (Scopus)

Abstract

CeO₂-ZrO₂ solid solution catalysis are very effective for the selective synthesis of dimethyl carbonate from methanol and CO₂. The activity was much dependent on the calcination temperature. The higher the calcination temperature, the higher the activity of the catalyst for DMC formation, though the BET surface area is lower on the catalyst calcined at higher temperature.

Original language	English
Pages (from-to)	71-74
Number of pages	4
Journal	Catalysis Letters
Volume	76
Issue number	1-2
DOIs	https://doi.org/10.1023/A:1016711722721
Publication status	Published - 2001 Sept

Keywords

Acidity
Basicity
CeO-ZrO solid solution
CO
Dimethyl carbonate
Methanol

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abstract = "CeO2-ZrO2 solid solution catalysis are very effective for the selective synthesis of dimethyl carbonate from methanol and CO2. The activity was much dependent on the calcination temperature. The higher the calcination temperature, the higher the activity of the catalyst for DMC formation, though the BET surface area is lower on the catalyst calcined at higher temperature.",

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AU - Furusawa, Yutaka

AU - Ikeda, Yoshiki

AU - Asadullah, Mohammad

AU - Fujimoto, Kaoru

PY - 2001/9

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AB - CeO2-ZrO2 solid solution catalysis are very effective for the selective synthesis of dimethyl carbonate from methanol and CO2. The activity was much dependent on the calcination temperature. The higher the calcination temperature, the higher the activity of the catalyst for DMC formation, though the BET surface area is lower on the catalyst calcined at higher temperature.

KW - Acidity

KW - Basicity

KW - CeO-ZrO solid solution

KW - CO

KW - Dimethyl carbonate

KW - Methanol

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CeO₂-ZrO₂ solid solution catalyst for selective synthesis of dimethyl carbonate from methanol and carbon dioxide

Abstract

Keywords

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