Change of micro and macro symmetry of barium titanate single crystal around Curie temperature and its model

S. Wada, T. Suzuki, T. Noma, M. Osada, M. Kakihana

    Research output: Contribution to conferencePaperpeer-review

    2 Citations (Scopus)

    Abstract

    Using high-quality barium titanate single crystals, its microscopic and macroscopic symmetries were investigated by a Raman scattering and a polarizing microscope, respectively. Their temperature dependences were also studied through Curie temperature. The microscopic symmetry of P4mm observed at 21.7 °C did not change through Curie temperature. On the other hand, the macroscopic symmetry was P4mm below 133.0 °C while that was Pm3m above 133.0 °C. This difference between the microscopic and macroscopic symmetries above Curie temperature suggested that the barium titanate above 133.0 °C has intrinsically some disordered behavior. We proposed the model, that the flipping behavior of the polar vector can be origin of the disordered behavior.

    Original languageEnglish
    Pages487-490
    Number of pages4
    Publication statusPublished - 1998 Dec 1
    EventProceedings of the 1998 11th IEEE International Symposium on Appliations of Ferroelectrics (ISAF-XI) - Montreaux, Switz
    Duration: 1998 Aug 241998 Aug 27

    Other

    OtherProceedings of the 1998 11th IEEE International Symposium on Appliations of Ferroelectrics (ISAF-XI)
    CityMontreaux, Switz
    Period98/8/2498/8/27

    ASJC Scopus subject areas

    • Electronic, Optical and Magnetic Materials
    • Electrical and Electronic Engineering

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