Characterization of PVA-NH4NO3 polymer electrolyte and its application in rechargeable proton battery

Subramaniyan Selvasekarapandian; Muthusamy Hema; Junichi Kawamura; Osamu Kamishima; Rangaswami Baskaran

doi:10.1143/JPSJS.79SA.163

Characterization of PVA-NH₄NO₃ polymer electrolyte and its application in rechargeable proton battery

Subramaniyan Selvasekarapandian, Muthusamy Hema, Junichi Kawamura, Osamu Kamishima, Rangaswami Baskaran

Research output: Contribution to journal › Article › peer-review

55 Citations (Scopus)

Abstract

The PVA-NH₄NO₃ polymer electrolytes have been prepared by solvent casting technique and characterized by XRD, FTIR, DSC, Raman, ¹H NMR and ac impedance spectroscopic studies to find out best composition possessing good electrical and mechanical stability. Using the best optimum composition, proton battery with two different cell configurations have been constructed and subjected to rechargeability studies. In the present study rechargeability up to 3 cycles without significant loss in the voltage has been obtained for the cell with configuration Zn + ZnSO₄.7H ₂O|80PVA: 20NH₄NO₃ | V₂O ₅+PbO₂+ C + PE.

Original language	English
Pages (from-to)	163-168
Number of pages	6
Journal	journal of the physical society of japan
Volume	79
Issue number	SUPPL. A
DOIs	https://doi.org/10.1143/JPSJS.79SA.163
Publication status	Published - 2010

Keywords

Polymer electrolyte
Proton battery
Solvent casting technique

ASJC Scopus subject areas

Physics and Astronomy(all)

Access to Document

10.1143/JPSJS.79SA.163

Cite this

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title = "Characterization of PVA-NH4NO3 polymer electrolyte and its application in rechargeable proton battery",

abstract = "The PVA-NH4NO3 polymer electrolytes have been prepared by solvent casting technique and characterized by XRD, FTIR, DSC, Raman, 1H NMR and ac impedance spectroscopic studies to find out best composition possessing good electrical and mechanical stability. Using the best optimum composition, proton battery with two different cell configurations have been constructed and subjected to rechargeability studies. In the present study rechargeability up to 3 cycles without significant loss in the voltage has been obtained for the cell with configuration Zn + ZnSO4.7H 2O|80PVA: 20NH4NO3 | V2O 5+PbO2+ C + PE.",

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T1 - Characterization of PVA-NH4NO3 polymer electrolyte and its application in rechargeable proton battery

AU - Selvasekarapandian, Subramaniyan

AU - Hema, Muthusamy

AU - Kawamura, Junichi

AU - Kamishima, Osamu

AU - Baskaran, Rangaswami

PY - 2010

Y1 - 2010

N2 - The PVA-NH4NO3 polymer electrolytes have been prepared by solvent casting technique and characterized by XRD, FTIR, DSC, Raman, 1H NMR and ac impedance spectroscopic studies to find out best composition possessing good electrical and mechanical stability. Using the best optimum composition, proton battery with two different cell configurations have been constructed and subjected to rechargeability studies. In the present study rechargeability up to 3 cycles without significant loss in the voltage has been obtained for the cell with configuration Zn + ZnSO4.7H 2O|80PVA: 20NH4NO3 | V2O 5+PbO2+ C + PE.

AB - The PVA-NH4NO3 polymer electrolytes have been prepared by solvent casting technique and characterized by XRD, FTIR, DSC, Raman, 1H NMR and ac impedance spectroscopic studies to find out best composition possessing good electrical and mechanical stability. Using the best optimum composition, proton battery with two different cell configurations have been constructed and subjected to rechargeability studies. In the present study rechargeability up to 3 cycles without significant loss in the voltage has been obtained for the cell with configuration Zn + ZnSO4.7H 2O|80PVA: 20NH4NO3 | V2O 5+PbO2+ C + PE.

KW - Polymer electrolyte

KW - Proton battery

KW - Solvent casting technique

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