(Chemical Equation Presented) A highly enantioselective anti-diastereoselective hetero-Diels-Alder reaction between a glyoxylate and siloxy- or methoxydienes using a chiral phosphoric acid catalyst that possesses less bulky phenyl groups at the 3 and 3′ positions of binaphthyl has been developed. The diastereoselectivities presented are disparate to those previously reported for hetero-Diels-Alder reactions catalyzed by a chiral Lewis acid.
|Number of pages||2|
|Journal||Journal of the American Chemical Society|
|Publication status||Published - 2009 Sept 16|
ASJC Scopus subject areas
- Colloid and Surface Chemistry