Chiral titanium complex-catalyzed carbonyl-ene reaction with glyoxylate: Remarkable positive nonlinear effect

Koichi Mikami; Masahiro Terada

doi:10.1016/0040-4020(92)80018-B

Chiral titanium complex-catalyzed carbonyl-ene reaction with glyoxylate: Remarkable positive nonlinear effect

Koichi Mikami, Masahiro Terada

SCI - Chemistry

Tokyo Institute of Technology

Research output: Contribution to journal › Article › peer-review

90 Citations (Scopus)

Abstract

The enantioselective glyoxylate-ene reaction catalyzed by chiral titanium complex derived from partially resolved binaphthol (BINOL) is shown to exhibit a remarkable level of asymmetric amplification (positive nonlinear effect). Thus, the optical yield of the ene product significantly exceeds the enantio-purity of the chiral ligand (BINOL).

Original language	English
Pages (from-to)	5671-5680
Number of pages	10
Journal	Tetrahedron
Volume	48
Issue number	27
DOIs	https://doi.org/10.1016/0040-4020(92)80018-B
Publication status	Published - 1992 Jul 3

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10.1016/0040-4020(92)80018-B

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title = "Chiral titanium complex-catalyzed carbonyl-ene reaction with glyoxylate: Remarkable positive nonlinear effect",

abstract = "The enantioselective glyoxylate-ene reaction catalyzed by chiral titanium complex derived from partially resolved binaphthol (BINOL) is shown to exhibit a remarkable level of asymmetric amplification (positive nonlinear effect). Thus, the optical yield of the ene product significantly exceeds the enantio-purity of the chiral ligand (BINOL).",

author = "Koichi Mikami and Masahiro Terada",

year = "1992",

month = jul,

day = "3",

doi = "10.1016/0040-4020(92)80018-B",

language = "English",

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number = "27",

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T1 - Chiral titanium complex-catalyzed carbonyl-ene reaction with glyoxylate

T2 - Remarkable positive nonlinear effect

AU - Mikami, Koichi

AU - Terada, Masahiro

PY - 1992/7/3

Y1 - 1992/7/3

N2 - The enantioselective glyoxylate-ene reaction catalyzed by chiral titanium complex derived from partially resolved binaphthol (BINOL) is shown to exhibit a remarkable level of asymmetric amplification (positive nonlinear effect). Thus, the optical yield of the ene product significantly exceeds the enantio-purity of the chiral ligand (BINOL).

AB - The enantioselective glyoxylate-ene reaction catalyzed by chiral titanium complex derived from partially resolved binaphthol (BINOL) is shown to exhibit a remarkable level of asymmetric amplification (positive nonlinear effect). Thus, the optical yield of the ene product significantly exceeds the enantio-purity of the chiral ligand (BINOL).

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U2 - 10.1016/0040-4020(92)80018-B

DO - 10.1016/0040-4020(92)80018-B

M3 - Article

AN - SCOPUS:0000582618

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VL - 48

SP - 5671

EP - 5680

JO - Tetrahedron

JF - Tetrahedron

IS - 27

ER -

Chiral titanium complex-catalyzed carbonyl-ene reaction with glyoxylate: Remarkable positive nonlinear effect

Abstract

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