Chiroselective transcription of the sugar structure to Δ- or Λ-[CoIII(bpy)3]3+ using a boronic acid-sugar template interaction

Toshihisa Mizuno; Masayuki Takeuchi; Itaru Hamachi; Kazuaki Nakashima; Seiji Shinkai

doi:10.1039/a704041e

Chiroselective transcription of the sugar structure to Δ- or Λ-[Co^III(bpy)₃]³⁺ using a boronic acid-sugar template interaction

Toshihisa Mizuno, Masayuki Takeuchi, Itaru Hamachi, Kazuaki Nakashima, Seiji Shinkai

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

In order to apply boronic acid-saccharide interactions to the chiroselective synthesis of Δ- and Λ-[Co^III(bpy)₃]³⁺ a saccharide-binding ligand, 2,2′-bipyridine-4,4′-diboronic acid (bpyba) is newly synthesized; the enantiomeric excess under the optimum reaction conditions reached 79% ee!.

Original language	English
Pages (from-to)	1793-1794
Number of pages	2
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/a704041e
Publication status	Published - 1997
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "In order to apply boronic acid-saccharide interactions to the chiroselective synthesis of Δ- and Λ-[CoIII(bpy)3]3+ a saccharide-binding ligand, 2,2′-bipyridine-4,4′-diboronic acid (bpyba) is newly synthesized; the enantiomeric excess under the optimum reaction conditions reached 79% ee!.",

author = "Toshihisa Mizuno and Masayuki Takeuchi and Itaru Hamachi and Kazuaki Nakashima and Seiji Shinkai",

year = "1997",

doi = "10.1039/a704041e",

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AU - Mizuno, Toshihisa

AU - Takeuchi, Masayuki

AU - Hamachi, Itaru

AU - Nakashima, Kazuaki

AU - Shinkai, Seiji

PY - 1997

Y1 - 1997

N2 - In order to apply boronic acid-saccharide interactions to the chiroselective synthesis of Δ- and Λ-[CoIII(bpy)3]3+ a saccharide-binding ligand, 2,2′-bipyridine-4,4′-diboronic acid (bpyba) is newly synthesized; the enantiomeric excess under the optimum reaction conditions reached 79% ee!.

AB - In order to apply boronic acid-saccharide interactions to the chiroselective synthesis of Δ- and Λ-[CoIII(bpy)3]3+ a saccharide-binding ligand, 2,2′-bipyridine-4,4′-diboronic acid (bpyba) is newly synthesized; the enantiomeric excess under the optimum reaction conditions reached 79% ee!.

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DO - 10.1039/a704041e

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Chiroselective transcription of the sugar structure to Δ- or Λ-[Co^III(bpy)₃]³⁺ using a boronic acid-sugar template interaction

Abstract

ASJC Scopus subject areas

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