Co-catalyzed radical cycloaddition of [60]fullerene with active dibromides: Selective synthesis of carbocycle-fused fullerene monoadducts

Shirong Lu; Weili Si; Ming Bao; Yoshinori Yamamoto; Tienan Jin

doi:10.1021/ol401876n

Co-catalyzed radical cycloaddition of [60]fullerene with active dibromides: Selective synthesis of carbocycle-fused fullerene monoadducts

Shirong Lu, Weili Si, Ming Bao, Yoshinori Yamamoto, Tienan Jin

SCI - Research and Analytical Center for Giant Molecules

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

An efficient and highly selective Co-catalyzed radical cycloaddition of [60]fullerene with active dibromides for the synthesis of three-, five-, six-, and seven-membered carbocycle-fused fullerene monoadducts has been reported. The controlled experiments unambiguously disclosed that the reaction proceeds through the formation of a fullerene monoradical as a key intermediate.

Original language	English
Pages (from-to)	4030-4033
Number of pages	4
Journal	Organic letters
Volume	15
Issue number	15
DOIs	https://doi.org/10.1021/ol401876n
Publication status	Published - 2013 Aug 2

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

Access to Document

10.1021/ol401876n

Cite this

@article{45d651253e904d6d946d9c99f5c3638b,

title = "Co-catalyzed radical cycloaddition of [60]fullerene with active dibromides: Selective synthesis of carbocycle-fused fullerene monoadducts",

abstract = "An efficient and highly selective Co-catalyzed radical cycloaddition of [60]fullerene with active dibromides for the synthesis of three-, five-, six-, and seven-membered carbocycle-fused fullerene monoadducts has been reported. The controlled experiments unambiguously disclosed that the reaction proceeds through the formation of a fullerene monoradical as a key intermediate.",

author = "Shirong Lu and Weili Si and Ming Bao and Yoshinori Yamamoto and Tienan Jin",

year = "2013",

month = aug,

day = "2",

doi = "10.1021/ol401876n",

language = "English",

volume = "15",

pages = "4030--4033",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "15",

}

TY - JOUR

T1 - Co-catalyzed radical cycloaddition of [60]fullerene with active dibromides

T2 - Selective synthesis of carbocycle-fused fullerene monoadducts

AU - Lu, Shirong

AU - Si, Weili

AU - Bao, Ming

AU - Yamamoto, Yoshinori

AU - Jin, Tienan

PY - 2013/8/2

Y1 - 2013/8/2

N2 - An efficient and highly selective Co-catalyzed radical cycloaddition of [60]fullerene with active dibromides for the synthesis of three-, five-, six-, and seven-membered carbocycle-fused fullerene monoadducts has been reported. The controlled experiments unambiguously disclosed that the reaction proceeds through the formation of a fullerene monoradical as a key intermediate.

AB - An efficient and highly selective Co-catalyzed radical cycloaddition of [60]fullerene with active dibromides for the synthesis of three-, five-, six-, and seven-membered carbocycle-fused fullerene monoadducts has been reported. The controlled experiments unambiguously disclosed that the reaction proceeds through the formation of a fullerene monoradical as a key intermediate.

UR - http://www.scopus.com/inward/record.url?scp=84881254967&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84881254967&partnerID=8YFLogxK

U2 - 10.1021/ol401876n

DO - 10.1021/ol401876n

M3 - Article

C2 - 23879528

AN - SCOPUS:84881254967

SN - 1523-7060

VL - 15

SP - 4030

EP - 4033

JO - Organic Letters

JF - Organic Letters

IS - 15

ER -

Co-catalyzed radical cycloaddition of [60]fullerene with active dibromides: Selective synthesis of carbocycle-fused fullerene monoadducts

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this