Cocrystals of Li+encapsulated fullerenes and Tb(iii) double-decker single molecule magnet in a quasi-kagome lattice

Hikaru Iwami, Junfei Xing, Ryo Nakanishi, Yoji Horii, Keiichi Katoh, Brian K. Breedlove, Kazuhiko Kawachi, Yasuhiko Kasama, Eunsang Kwon, Masahiro Yamashita

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Cocrystallization of a lithium ion encapsulated fullerene Li+@C60 with a terbium(iii) phthalocyaninato porphyrinato double-decker single-molecule magnet [Tb(Pc)(OEP)] is reported. The cocrystal, containing PF6- as a counter anion, packs in a quasi-kagome lattice, which leads to intermolecular ferromagnetic interactions as well as the modulation of the single-molecule magnet (SMM) properties.

Original languageEnglish
Pages (from-to)12785-12788
Number of pages4
JournalChemical Communications
Volume56
Issue number84
DOIs
Publication statusPublished - 2020 Oct 28

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