Complexation of lanthanide ions with polymerizable macrocyclic calixarene derivatives for polymer optical device applications

Rahmat Hidayat; Okihiro Sugihara; Masaaki Tsuchimori; Manabu Kagami; Tadatomi Nishikubo; Toshikuni Kaino

Complexation of lanthanide ions with polymerizable macrocyclic calixarene derivatives for polymer optical device applications

Rahmat Hidayat, Okihiro Sugihara, Masaaki Tsuchimori, Manabu Kagami, Tadatomi Nishikubo, Toshikuni Kaino

Research output: Contribution to journal › Article › peer-review

Abstract

Incorporation of lanthanide ions in polymerizable macrocylic molecules, such as calixarene and calix- resorcinarene monomers, has been studied by ¹H NMR and fluorescence spectroscopies. The complexation formation through non-ionic coordination bond with the upper rim oxygen of resorcinarene monomers was clarified by the observation of dipolar shift in NMR spectrum. The complexation results in broadening of fluorescence peak and elongation of the fluorescence decay, which are attributed to increasing anisotropy of ligand field due to this complexation.

Original language	English
Pages (from-to)	91-94
Number of pages	4
Journal	Nonlinear Optics Quantum Optics
Volume	34
Issue number	1-4 SPEC. ISS.
Publication status	Published - 2005
Externally published	Yes

Keywords

Europium complex
Fluorescence
Lanthanide
Ligand field
Macrocyclic
Polymer

ASJC Scopus subject areas

Statistical and Nonlinear Physics
Electronic, Optical and Magnetic Materials
Computer Science(all)
Atomic and Molecular Physics, and Optics
Instrumentation

Cite this

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title = "Complexation of lanthanide ions with polymerizable macrocyclic calixarene derivatives for polymer optical device applications",

abstract = "Incorporation of lanthanide ions in polymerizable macrocylic molecules, such as calixarene and calix- resorcinarene monomers, has been studied by 1H NMR and fluorescence spectroscopies. The complexation formation through non-ionic coordination bond with the upper rim oxygen of resorcinarene monomers was clarified by the observation of dipolar shift in NMR spectrum. The complexation results in broadening of fluorescence peak and elongation of the fluorescence decay, which are attributed to increasing anisotropy of ligand field due to this complexation.",

keywords = "Europium complex, Fluorescence, Lanthanide, Ligand field, Macrocyclic, Polymer",

author = "Rahmat Hidayat and Okihiro Sugihara and Masaaki Tsuchimori and Manabu Kagami and Tadatomi Nishikubo and Toshikuni Kaino",

year = "2005",

language = "English",

volume = "34",

pages = "91--94",

journal = "Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics",

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T1 - Complexation of lanthanide ions with polymerizable macrocyclic calixarene derivatives for polymer optical device applications

AU - Hidayat, Rahmat

AU - Sugihara, Okihiro

AU - Tsuchimori, Masaaki

AU - Kagami, Manabu

AU - Nishikubo, Tadatomi

AU - Kaino, Toshikuni

PY - 2005

Y1 - 2005

N2 - Incorporation of lanthanide ions in polymerizable macrocylic molecules, such as calixarene and calix- resorcinarene monomers, has been studied by 1H NMR and fluorescence spectroscopies. The complexation formation through non-ionic coordination bond with the upper rim oxygen of resorcinarene monomers was clarified by the observation of dipolar shift in NMR spectrum. The complexation results in broadening of fluorescence peak and elongation of the fluorescence decay, which are attributed to increasing anisotropy of ligand field due to this complexation.

AB - Incorporation of lanthanide ions in polymerizable macrocylic molecules, such as calixarene and calix- resorcinarene monomers, has been studied by 1H NMR and fluorescence spectroscopies. The complexation formation through non-ionic coordination bond with the upper rim oxygen of resorcinarene monomers was clarified by the observation of dipolar shift in NMR spectrum. The complexation results in broadening of fluorescence peak and elongation of the fluorescence decay, which are attributed to increasing anisotropy of ligand field due to this complexation.

KW - Europium complex

KW - Fluorescence

KW - Lanthanide

KW - Ligand field

KW - Macrocyclic

KW - Polymer

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SN - 1543-0537

VL - 34

SP - 91

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JO - Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics

JF - Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics

IS - 1-4 SPEC. ISS.

ER -

Complexation of lanthanide ions with polymerizable macrocyclic calixarene derivatives for polymer optical device applications

Abstract

Keywords

ASJC Scopus subject areas

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