Composition and stability of decagonal quasicrystals in the Zn-Mg-rare-earth systems

Taku J. Sato, Eiji Abe, An Pang Tsai

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48 Citations (Scopus)

Abstract

Decagonal quasicrystals in Zn-Mg-RE systems (RE = rare earth) have been studied for their composition and stability. The decagonal phase was shown to have the composition Zn58Mg4oDy2in the Zn-Mg-Dy system. This phase became a major phase after annealing and thus is apparently thermodynamically stable. Further, the decagonal phase was observed for RE = Y, Dy, Ho, Er, Tm and Lu.o All these RE elements have Goldschmidt atomic diameters smaller than 3.55 A, suggesting that the atomic diameter is an intrinsic parameter in stabilizing the decagonal phase.

Original languageEnglish
Pages (from-to)213-219
Number of pages7
JournalPhilosophical Magazine Letters
Volume77
Issue number4
DOIs
Publication statusPublished - 1998 Apr

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