Computational studies of effective asymmetric alkylation utilizing a chiral Schiff base derived from 2-hydroxy-3-pinanone - Part 1

Takatoshi Matsumoto; Takayuki Shioiri; Eiji Osawa

doi:10.1016/0040-4020(96)00226-8

Computational studies of effective asymmetric alkylation utilizing a chiral Schiff base derived from 2-hydroxy-3-pinanone - Part 1

Takatoshi Matsumoto, Takayuki Shioiri, Eiji Osawa

IMRAM - Division of Measurements

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The calculation by the semi-empirical molecular orbital method concerning the mechanism of the effective asymmetric alkylation utilizing a chiral Schiff base derived from 2-hydroxy-3-pinanone (2) has revealed that the factor which controls the stereoselectivity is mainly the influence of the lithium and THF ligands. The result has demonstrated the proposed hypothesis which is based on many experiments.

Original language	English
Pages (from-to)	5961-5970
Number of pages	10
Journal	Tetrahedron
Volume	52
Issue number	16
DOIs	https://doi.org/10.1016/0040-4020(96)00226-8
Publication status	Published - 1996 Apr 15

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title = "Computational studies of effective asymmetric alkylation utilizing a chiral Schiff base derived from 2-hydroxy-3-pinanone - Part 1",

abstract = "The calculation by the semi-empirical molecular orbital method concerning the mechanism of the effective asymmetric alkylation utilizing a chiral Schiff base derived from 2-hydroxy-3-pinanone (2) has revealed that the factor which controls the stereoselectivity is mainly the influence of the lithium and THF ligands. The result has demonstrated the proposed hypothesis which is based on many experiments.",

author = "Takatoshi Matsumoto and Takayuki Shioiri and Eiji Osawa",

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AU - Osawa, Eiji

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AB - The calculation by the semi-empirical molecular orbital method concerning the mechanism of the effective asymmetric alkylation utilizing a chiral Schiff base derived from 2-hydroxy-3-pinanone (2) has revealed that the factor which controls the stereoselectivity is mainly the influence of the lithium and THF ligands. The result has demonstrated the proposed hypothesis which is based on many experiments.

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Computational studies of effective asymmetric alkylation utilizing a chiral Schiff base derived from 2-hydroxy-3-pinanone - Part 1

Abstract

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