Control of absorption properties of tetraazaporphyrin group 15 complexes by modification of their axial ligands

Taniyuki Furuyama; Mitsuo Asai; Nagao Kobayashi

doi:10.1039/c4cc07408d

Control of absorption properties of tetraazaporphyrin group 15 complexes by modification of their axial ligands

Taniyuki Furuyama, Mitsuo Asai, Nagao Kobayashi

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Tetraazaporphyrin (TAP) complexes with group 15 elements (phosphorus(V) or arsenic(V)) containing two axial OH ligands showed reversible spectroscopic changes with acid or base doping. Spectroscopic and theoretical analysis revealed that the modification of axial ligands can tune the interaction between peripheral substituents and the TAP macrocycle.

Original language	English
Pages (from-to)	15101-15104
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	95
DOIs	https://doi.org/10.1039/c4cc07408d
Publication status	Published - 2014 Nov 4

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "Tetraazaporphyrin (TAP) complexes with group 15 elements (phosphorus(V) or arsenic(V)) containing two axial OH ligands showed reversible spectroscopic changes with acid or base doping. Spectroscopic and theoretical analysis revealed that the modification of axial ligands can tune the interaction between peripheral substituents and the TAP macrocycle.",

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AU - Furuyama, Taniyuki

AU - Asai, Mitsuo

AU - Kobayashi, Nagao

PY - 2014/11/4

Y1 - 2014/11/4

N2 - Tetraazaporphyrin (TAP) complexes with group 15 elements (phosphorus(V) or arsenic(V)) containing two axial OH ligands showed reversible spectroscopic changes with acid or base doping. Spectroscopic and theoretical analysis revealed that the modification of axial ligands can tune the interaction between peripheral substituents and the TAP macrocycle.

AB - Tetraazaporphyrin (TAP) complexes with group 15 elements (phosphorus(V) or arsenic(V)) containing two axial OH ligands showed reversible spectroscopic changes with acid or base doping. Spectroscopic and theoretical analysis revealed that the modification of axial ligands can tune the interaction between peripheral substituents and the TAP macrocycle.

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JO - Chemical Communications

JF - Chemical Communications

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Control of absorption properties of tetraazaporphyrin group 15 complexes by modification of their axial ligands

Abstract

ASJC Scopus subject areas

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